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methyl aziridine-1-carboxylate
aniline
A
ethyleneimine
B
(2-Phenylamino-ethyl)-carbamic acid methyl ester
Conditions | Yield |
---|---|
In ethanol at 18 - 25℃; for 480h; | A n/a B 98% |
1-(phenylaminocarbonyl)aziridine
dimethyl amine
A
ethyleneimine
B
fenuron
Conditions | Yield |
---|---|
In ethanol at 18 - 25℃; for 168h; | A n/a B 94% |
piperidine
methyl aziridine-1-carboxylate
A
ethyleneimine
B
(2-Piperidin-1-yl-ethyl)-carbamic acid methyl ester
Conditions | Yield |
---|---|
In ethanol at 18 - 25℃; for 24h; | A n/a B 92% |
1-(phenylaminocarbonyl)aziridine
methylamine
A
ethyleneimine
B
1-methyl-3-phenylurea
Conditions | Yield |
---|---|
In ethanol at 18 - 25℃; for 168h; | A n/a B 92% |
Conditions | Yield |
---|---|
With ammonia In ethanol at 18 - 25℃; for 24h; | A n/a B 90% |
Conditions | Yield |
---|---|
With 1 M DTPP at 60℃; for 48h; | 90% |
With BNTP In dichloromethane at 40℃; for 24h; | 98 % Chromat. |
With potassium hydroxide; sulfuric acid 1.) 80 deg C, overnight; Multistep reaction; | |
With cesium nitrate; iron nitrate; magnesium nitrate on fluoridated P2O5/SiO2/TiO2 at 370℃; for 8h; Temperature; Reagent/catalyst; Inert atmosphere; chemoselective reaction; |
morpholine
methyl aziridine-1-carboxylate
A
ethyleneimine
B
(2-Morpholin-4-yl-ethyl)-carbamic acid methyl ester
Conditions | Yield |
---|---|
In ethanol at 18 - 25℃; for 24h; | A n/a B 88% |
Conditions | Yield |
---|---|
With ammonia In ethanol at 18 - 25℃; for 168h; | A n/a B 88% |
methyl aziridine-1-carboxylate
dimethyl amine
A
ethyleneimine
B
1-methoxycarbonylamino-2-dimethylaminoethane
Conditions | Yield |
---|---|
In ethanol at 18 - 25℃; for 24h; | A n/a B 82% |
Conditions | Yield |
---|---|
With carbon dioxide; DBN; lithium iodide In toluene at 90℃; for 5h; Inert atmosphere; | 82% |
MF: C2H5N
MW: 43.07
EINECS: 205-793-9
Product Categories: Pharmaceutical Intermediates
Mol File: 151-56-4.mol
mp: -78°C
bp: 56°C
density: 0,83 g/cm3
Fp: -11°C
Water Solubility: miscible
Synonyms:AZIRIDINE;ETHYLENEIMINE;ETHYLENIMINE;Dimethyleneimine;1H-Azirine, dihydro-;Aethylenimin;Aminoethylene;Azacyclopropane
The structure of Ethyleneimine(151-56-4) is:
1. | eye-mus 2 ppm/1M | JIHTAB Journal of Industrial Hygiene and Toxicology. 30 (1948),7. | ||
2. | skn-rbt 10 mg/24H open | JIHTAB Journal of Industrial Hygiene and Toxicology. 30 (1948),63. | ||
3. | eye-rbt 2 mg SEV | AJOPAA American Journal of Ophthalmology. 29 (1946),1363. | ||
4. | sln-dmg-mul 1 pph/8H-C | GNKAA5 Genetika. 21 (1985),958. | ||
5. | mnt-nml-mul 5000 ppm/8D-C | MUREAV Mutation Research. 125 (1984),275. | ||
6. | cyt-hmn:lng 1 µmol/L | EVSRBT Environmental Science Research. 24 (1981),433. | ||
7. | dns-mus-par 5 mg/kg | EVSRBT Environmental Science Research. 24 (1981),943. | ||
8. | dlt-mus-ipr 5 mg/kg | EVSRBT Environmental Science Research. 24 (1981),943. | ||
9. | msc-ham:ovr 2 mg/L | MUREAV Mutation Research. 94 (1982),449. | ||
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Hazard Codes: F;T,T,F,N,T+
Risk Statements:Very Toxic by inhalation;Very Toxic in contact with skin;Very Toxic if swallowed
Safety Statements:In case of accident or if you feel unwell, seek medical advice immediately;Avoid exposure - obtain special instruction before use
RIDADR: 1185
HazardClass: 6.1(a)
PackingGroup: I
Hazardous Substances Data: 151-56-4(Hazardous Substances Data)
Poison by ingestion, skin contact, inhalation, and intraperitoneal routes. Human mutation data reported. A skin, mucous membrane, and severe eye irritant. An allergic sensitizer of skin. Causes opaque cornea, keratoconus, and necrosis of cornea (experimentally). Has been known to cause severe human eye injury. Drinking of carbonated beverages is recommended as an antidote to this material in stomach.