Addition of chlorodisilanes to acetylene catalyzed by tetrakis(triphenylphosphine)palladium(0). a facile route to (Z)-1,2-bis(chlorosilyl)ethenes

Add time:07/16/2019    Source:sciencedirect.com

In the presence of a catalytic amount of tetrakis(triphenylphosphine)palladium(0), chlorodisilanes of type MenSi2Cl6−n (n = 2–5) add to acetylene to afford 1,2-bis(chlorosilyl)ethenes in reasonable yields.

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