Diastereo- and enantioselective preparation of β-alkylhomoallylic alcohols

Add time:07/21/2019    Source:sciencedirect.com

A new and efficient method for the preparation of four possible stereoisomers of β-alkylhomoallylic alcohols 1 has been developed which is based on the diastereoselective addition of nucleophiles to optically active α-alkyl-β-trimethylsilyl-β,γ-unsaturated carbonyl compounds. The utility of this reaction is demonstrated by the synthesis of naturally occurring serricornin and corynomycolic acid.

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