Infrared spectra and rotational isomerization of 1-bromo-3-methyl-2-butene

Add time:07/21/2019    Source:sciencedirect.com

Infrared spectra obtained for the title compound, (CH3)2CCH. CH2Br, have revealed the co-existence of two rotational isomeric forms in the fluid phases, the geometrical structures of which cannot be ascertained by use of vibrational spectroscopy alone. The energy ditterence between the two isomers was found to be 1.1 kcal mol−1 (mean value) in the liquid state. Some of the i.r. fundamental bands were assigned using the characteristic absorption frequencies of localized group.

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