Detail of "768-95-6"

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CAS Number:
768-95-6
Name:
1-Adamantanol
Molecular Structure:
Formula:
C₁₀H₁₆O
Molecular Weight:
152.24
Synonyms:
Tricyclo(3.3.1.1(sup 3,7))decan-1-ol (9CI);1-Adamantol;Tricyclo[3.3.1.13,7]decan-1-ol;Adapalene-1;1-Ad-OH;Tricyclo(3.3.1.13,7)decan-1-ol;1-Hydroxyadamantane;adamantan-1-ol;tricyclo[3.3.1.1~3,7~]decan-1-ol;
EINECS:
212-202-8
Density:
1.16 g/cm³
Melting Point:
247 °C (subl.)(lit.)
Boiling Point:
245.8 °C at 760 mmHg
Flash Point:
101.131 °C
Appearance:
white to off-white crystalline powder or needles
Hazard Symbols:
Xi
Risk Codes:
36/37/38
Safety:
22-24/25-36-26 Details

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Reference

Adamantane derivatives: a new class of insulin secretagogues: Adamantane derivatives: a new class of insulin secretagogues. Garrino, M. G.; Henquin, J. C. (Unite Diabetol. Nutr., Univ.Chemicals with cas numbers 281-23-2 and 13074-39-0 also play role. Louvain, Brussels B-1200, Belg.). Br. J. Pharmacol., 90(3), 583-91 (English) 1987. CODEN: BJPCBM. ISSN: 0007-1188. DOCUMENT TYPE: Journal CA Section: 1 (Pharmacology) Adamantane derivs. increased insulin [9004-10-8] release in vitro. Mouse islets were used to study the mechanisms and mol. requirements of that hitherto unrecognized property. At a non-stimulatory concn. of glucose (3 mM), 1-adamantanamine [768-94-5] (1 mM) reversibly inhibited 86Rb efflux from islet cells, depolarized the b-cell membrane, induced elec. activity, stimulated 45Ca uptake and efflux, and triggered insulin release. Omission of extracellular Ca2+ abolished the secretory response but only partially inhibited the acceleration of 45Ca efflux. At a stimulatory concn. of glucose (10 mM), 1-adamantanamine reversibly increased 86Rb efflux, potentiated elec. activity (lengthening of the slow waves with spikes), augmented 45Ca uptake and efflux, and increased insulin release. The effects of adamantanamine were dose-dependent, with a threshold concn. of 10 mM for stimulation of release. 2-Adamantanamine [13074-39-0] was as potent as 1-adamantanamine. In contrast, substitution of the amino group by a carboxyl group (1-adamantanecarboxylic acid [828-51-3]) decreased the effectiveness by about 65%, and substitution by a hydroxyl group (1-adamantanol [768-95-6]) suppressed it. .

Mechanism of the action of two-dimensional condensed layers of org: Mechanism of the action of two-dimensional condensed layers of org. substances on the kinetics of electrochemical reactions. Stenina, E. V.; Fedorovich, N. V.; Damaskin, B. B.; Girlya, L. N. (Mosk. Gos. Univ., Moscow, USSR). Dokl. Akad. Nauk SSSR, 273(2), 389-92 [Phys. Chem.] (Russian) 1983. CODEN: DANKAS. ISSN: 0002-3264. DOCUMENT TYPE: Journal CA Section: 72 (Electrochemistry) Section cross-reference(s): 67 An exptl. and theor. basis was sought for the mechanism of action of 2-dimensional condensed layers of 3-hydroxyhomoadamantane (I) [14504-80-4] and 1-adamantanol [768-95-6] on the kinetics of the discharge reaction of anions (e.g. BrO4- and S2O82-). A characteristic of the curves of the dependence of the differential capacitance on the potential for such layers is the absence of adsorption-desorption peaks and a sharp drop in the capacitance corresponding to the 2-dimensional phase transition from q = 0 to q = 1. The introduction of I into the soln. leads to the inhibition of the discharge reaction of S2O82- in all the range of adsorption potentials, while the effect of the 2-dimensional condensed layer of I on the reaction rate is so great, that in a soln. with addns. of this substance there is obsd. a dependence of the reaction rate on the potential and compn. of the soln. emerging from the theory of slowed discharge.

Detail of "768-95-6"

1-Adamantanol

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Reference