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Conditions | Yield |
---|---|
With dihydrogen peroxide In tetrahydrofuran; water; acetic acid for 30h; Ambient temperature; | 100% |
Conditions | Yield |
---|---|
Stage #1: methyl salicylate With lithium aluminium tetrahydride In tetrahydrofuran at 20℃; for 3h; Inert atmosphere; Stage #2: With hydrogenchloride In tetrahydrofuran; water; ethyl acetate at 0℃; Inert atmosphere; | 100% |
With lithium aluminium tetrahydride In 2-methyltetrahydrofuran at -15 - 20℃; for 24.16h; | 93% |
With zinc(II) tetrahydroborate; cyclohexene In tetrahydrofuran for 4h; Heating; | 70% |
With lithium aluminium tetrahydride In diethyl ether | |
With C21H24N4Ru(1+)*F6P(1-); potassium tert-butylate; hydrogen In tetrahydrofuran at 50℃; under 18751.9 Torr; for 4h; Catalytic behavior; |
Conditions | Yield |
---|---|
With tri-n-butyl-tin hydride In methanol; diethyl ether for 4h; Reduction; Heating; | 100% |
With N-methylpyrrolidine zinc borohydride In tetrahydrofuran at 20℃; for 0.166667h; | 100% |
With Zr(BH4)2Cl2(dabco)2 In water for 0.8h; Heating; | 93% |
salicylic alcohol
Conditions | Yield |
---|---|
With water | 100% |
Conditions | Yield |
---|---|
With formic acid; C20H29ClIrN4(1+)*Cl(1-) In water at 80℃; for 0.166667h; chemoselective reaction; | 99% |
With hydrogen for 0.583333h; | 98% |
With (7,8-benzoquinolinato)hydrido(aqua)bis(triphenylphosphine)iridium(III) tetrakis[3,5-bis(trifluoromethyl)phenyl]borate; hydrogen; N-ethyl-N,N-diisopropylamine In toluene at 80℃; under 760.051 Torr; for 4h; | 98% |
1-(tert-butyldimethylsilanyloxy)-2-(tert-butyldimethylsilanyloxymethyl)benzene
salicylic alcohol
Conditions | Yield |
---|---|
With phosphomolybdic acid hydrate; silica gel In tetrahydrofuran at 20℃; for 18h; | 99% |
With tetrabutyl ammonium fluoride In tetrahydrofuran at 0℃; for 0.25h; |
Conditions | Yield |
---|---|
With sodium tetrahydroborate; Trimethyl borate; dimethyl sulfate In tetrahydrofuran at 20℃; for 4.5h; Product distribution; Further Variations:; Reagents; reagent ratios; | 98% |
With [Zn(BH4)2(py)] In tetrahydrofuran for 1.5h; Heating; | 93% |
With lithium aluminium tetrahydride In diethyl ether at 23℃; for 5h; Inert atmosphere; | 93% |
1-Trimethylsilanyloxy-2-trimethylsilanyloxymethyl-benzene
salicylic alcohol
Conditions | Yield |
---|---|
With methanol; 1,3-disulfonic acid imidazolium hydrogen sulfate at 20℃; for 0.0666667h; Green chemistry; | 98% |
With Nafion-H(R); silica gel In hexane at 20℃; for 0.5h; | 95% |
With montmorillonite K-10 In methanol for 0.7h; Ambient temperature; | 90% |
With nano magnetic sulfated zirconia (Fe3O4 at ZrO2/SO42-) In neat (no solvent) at 20℃; for 0.833333h; Green chemistry; | 80% |
2-((methoxymethoxy)methyl)phenol
salicylic alcohol
Conditions | Yield |
---|---|
phosphotungstic acid In ethanol for 2h; Heating; | 96% |
With 1-methylimidazole hydrogen sulfate at 120℃; for 0.0416667h; Microwave irradiation; chemoselective reaction; | 90% |
2-[(ethoxymethoxy)methyl]phenol
salicylic alcohol
Conditions | Yield |
---|---|
With 1-methylimidazole hydrogen sulfate at 120℃; for 0.0333333h; Microwave irradiation; chemoselective reaction; | 94% |
phosphotungstic acid In ethanol for 3.5h; Heating; | 90% |
2-HYDROXYMETHYLPHENOL(90-01-7) is an organic compound with the formula of C7H8O2 ,its chemical name is 2-Hydroxybenzyl alcohol and the formula weight is 124.14g/mol
CAS No.: 90-01-7
EINECS: 201-960-5
RTECS: DO6430000
RTECS Class: Reproductive Effector
IUPAC NAME: 2-(hydroxymethyl)phenol
Chemical Structure:
The chemical synonymous of 2-HYDROXYMETHYLPHENOL(90-01-7) are 2-Dihydroxytoluene;2-hydroxy-benzenemethano;2-Hydroxybenzenemethanol;2-hydroxy-Benzenemethanol;2-Hydroxymethylphenol;alpha,2-Dihydroxytoluene;alpha-Hydroxy-o-cresol;Benzenemethanol, 2-hydroxy- and so on.
The density of 2-HYDROXYMETHYLPHENOL(90-01-7) is 1,613 g/cm3and it has a melting point of 83-85 °C(lit.).The boiling point is 267.5 °C at 760 mmHg.Its flash point is 133.7 °C.The water solubility should be equal to 67 g/L (22 oC).
Appearance: light brown crystalline powder
Product Categories about 2-HYDROXYMETHYLPHENOL(90-01-7) is mainly Aromatics .
2-HYDROXYMETHYLPHENOL(90-01-7) is used for the pharmaceutical industry and used as a medicine, perfume, pesticide intermediates
An experimental teratogen. Experimental reproductive effects. When heated to decomposition it emits acrid smoke and irritating fumes.
Hazard Codes:
Xi: Irritant
Risk Statements about 2-HYDROXYMETHYLPHENOL(90-01-7):
R36/37/38 Irritating to eyes, respiratory system and skin.
Safety Statements about 2-HYDROXYMETHYLPHENOL(90-01-7):
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36 Wear suitable protective clothing.
Stability: Stable. Incompatible with acids, acid chlorides, acid anhydrides, strong oxidizing agents.
Storage:Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances.
Handling:Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
Fire Fighting:Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.Use agent most appropriate to extinguish fire.