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Name 2-Methoxy-1-propanol
EINECS216-455-5
CAS No. 1589-47-5
Density0.912 g/cm³
PSA29.46000
LogP0.01360
SolubilityN/A
Melting Point-84.2°C (estimate)
FormulaC4H10 O2
Boiling Point130 °C at 760 mmHg
Molecular Weight90.1222
Flash Point41.9 °C
Transport InformationUN 1993
AppearanceN/A
SafetyExperimental reproductive effects. When heated to decomposition it emits acrid smoke and irritating vapors.
Risk Codes61-10-37/38-41 2
Molecular Structure
Hazard SymbolsA reproductive hazard.
SynonymsA reproductive hazard.
Article Data84

2-Methoxy-1-propanol Synthetic route

: 67-56-1
methanol

: 75-56-9, 16033-71-9
methyloxirane

: 1589-47-5
2-methoxypropanol

Conditions

Conditions	Yield
With C2H3N4(1-)0.5C8H4O4(2-)Zn(2+) for 6h; Heating;	95.4%

: 67-56-1
methanol

: 75-56-9, 16033-71-9
methyloxirane

A: 107-98-2
1-methoxy-2-propanol

B: 1589-47-5
2-methoxypropanol

Conditions

Conditions	Yield
With MCM-41-encapsulated cetyltrimethylammonium hydroxide at 110℃; for 3h; regioselective reaction;	A 92% B n/a
With boron trifluoride diethyl etherate	A 36% B 39%
at 200℃;

: 187737-37-7
propene

A: 57-55-6
propylene glycol

B: 107-98-2
1-methoxy-2-propanol

C: 1589-47-5
2-methoxypropanol

D: 75-56-9, 16033-71-9
methyloxirane

Conditions

Conditions	Yield
With dihydrogen peroxide; titanium-silicate In methanol at 40℃;	A n/a B n/a C n/a D 92%
With dihydrogen peroxide; titanium-silicate In methanol at 40℃;	A n/a B n/a C n/a D 78%
With dihydrogen peroxide; titanium-silicate In water at 30 - 80℃; under 18751.9 Torr; pH=4.5;	A n/a B n/a C n/a D 61%

: 67-56-1
methanol

: 15448-47-2
(R)-propylene oxide

A: 4984-22-9
(R)-1-methoxy-2-propanol

B: 1589-47-5
2-methoxypropanol

Conditions

Conditions	Yield
With sodium hydroxide for 5h; Reflux;	A 79% B n/a

: 67-56-1
methanol

: 124-38-9
carbon dioxide

: 75-56-9, 16033-71-9
methyloxirane

A: 108-32-7
1,2-propylene cyclic carbonate

B: 57-55-6
propylene glycol

C: 107-98-2
1-methoxy-2-propanol

D: 1589-47-5
2-methoxypropanol

E: 616-38-6
carbonic acid dimethyl ester

Conditions

Conditions	Yield
With 6,7,9,10,12,13,20,21-octahydrodibenzo[b,h][1,4,7,10,13,16]hexaoxacyclooctadecine; potassium chloride at 130℃; under 15001.5 Torr; for 8h; Reagent/catalyst; Autoclave; High pressure;	A 69.2% B 12.5% C n/a D n/a E 13.2%
With 6,7,9,10,12,13,20,21-octahydrodibenzo[b,h][1,4,7,10,13,16]hexaoxacyclooctadecine; potassium bromide at 130℃; under 15001.5 Torr; for 8h; Reagent/catalyst; Autoclave; High pressure;	A 62.9% B 14.4% C n/a D n/a E 12.5%
With potassium bromide at 130℃; under 15001.5 Torr; for 8h; Autoclave; High pressure;	A 44.1% B 6.7% C n/a D n/a E 5.8%

...Expand

: 67-56-1
methanol

: 75-56-9, 16033-71-9
methyloxirane

A: 107-98-2
1-methoxy-2-propanol

B: 1589-47-5
2-methoxypropanol

C: 127-00-4
1-Chloro-2-propanol

Conditions

Conditions	Yield
With Cu(L-Asp)(1,2-bis(4-pyridyl)ethylene)0.5(H2O)0.5(MeOH)0.5 at 25℃;	A 56% B 40% C 4%
With Cu(L-Asp)(1,2-bis(4-pyridyl)ethylene)0.5(H2O)0.5(MeOH)0.5 at 60℃;	A 49% B 47% C 4%

: 67-56-1
methanol

: 124-38-9
carbon dioxide

: 75-56-9, 16033-71-9
methyloxirane

A: 108-32-7
1,2-propylene cyclic carbonate

B: 107-98-2
1-methoxy-2-propanol

C: 1589-47-5
2-methoxypropanol

Conditions

Conditions	Yield
With lithium iodide at 130℃; under 15001.5 Torr; for 8h; Reagent/catalyst; Autoclave; High pressure;	A 54.8% B n/a C n/a
With potassium carbonate at 100℃; for 6h; Supercritical conditions; Green chemistry;	A 35.6% B n/a C n/a

...Expand

: 67-56-1
methanol

: 124-38-9
carbon dioxide

: 75-56-9, 16033-71-9
methyloxirane

A: 108-32-7
1,2-propylene cyclic carbonate

B: 57-55-6
propylene glycol

C: 107-98-2
1-methoxy-2-propanol

D: 1589-47-5
2-methoxypropanol

Conditions

Conditions	Yield
With lithium bromide at 130℃; under 15001.5 Torr; for 8h; Autoclave; High pressure;	A 52.4% B 5.7% C n/a D n/a

...Expand

: 186581-53-3, 908094-01-9
diazomethane

: 57-55-6
propylene glycol

A: 107-98-2
1-methoxy-2-propanol

B: 1589-47-5
2-methoxypropanol

Conditions

Conditions	Yield
With H(+)-zeolite-X In benzene at 25℃; for 0.5h; Product distribution; further alcohols, thiols, aminoalcohols; further catalyst;	A 51% B 33%
With H(+)-zeolite-X In benzene at 25℃; for 0.5h;	A 51 % Chromat. B 33 % Chromat.
With sulfuric acid In benzene at 25℃; for 0.5h;	A 37 % Chromat. B 38 % Chromat.

: 534-15-6
1,1-dimethoxyethane

A: 6142-38-7
2-methoxypropanal

B: 1589-47-5
2-methoxypropanol

Conditions

Conditions	Yield
With carbon monoxide; hydrogen; cobalt at 200℃; under 661957 Torr;

2-Methoxy-1-propanol Chemical Properties

IUPAC Name: 2-Methoxypropan-1-ol
Molecular Formula: C₄H₁₀O₂
Molecular Weight: 90.14g/mol
EINECS: 216-455-5
Density: 0.912 g/cm³
Liansport Information: UN 1993
Density: 0.912 g/cm³
Boiling Point: 130 °C at 760 mmHg
Flash Point: 41.9 °C
Freely Rotating Bonds: 3
Polar Surface Area: 18.46Å²
Index of Refraction: 1.397
Molar Refractivity: 23.81 cm³
Molar Volume: 98.8 cm³
Polarizability: 9.44× 10^-24 cm³
Surface Tension: 26.9 dyne/cm
Enthalpy of Vaporization: 42.84 kJ/mol
Vapour Pressure: 4.44 mmHg at 25°C
2-Methoxy-1-propanol ,its Cas Register Number is 1589-47-5.The chemical synonyms of 2-Methoxy-1-propanol (CAS No.1589-47-5) are 2-Methoxypropanol ; 2-Methoxy-1-propanol ; 1-Propanol, 2-methoxy- ; 1-Propyleneglycol-2-methylether ; Beta-propyleneglycolmonomethylether ; 2-Methoxypropanol-1 ; 2-Methoxy-1-propano .The molecular structure of 2-Methoxy-1-propanol (CAS No.1589-47-5) is.

2-Methoxy-1-propanol Uses

2-Methoxy-1-propanol (CAS No.1589-47-5) is used in organic synthesis.

2-Methoxy-1-propanol Consensus Reports

Reported in EPA TSCA Inventory.

2-Methoxy-1-propanol Safety Profile

Experimental reproductive effects. When heated to decomposition it emits acrid smoke and irritating vapors.
Hazard Codes: Very T
Risk Statements: 61-10-37/38-41
R61:May cause harm to the unborn child.
R10:Flammable.
R41:Risk of serious damage to the eyes.
R37/38:Irritating to respiratory system and skin.
Safety Statements: 53-45
S53:Avoid exposure - obtain special instructions before use.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
HazardClass: 3.2

2-Methoxy-1-propanol Standards and Recommendations

OSHA PEL: OSHA Analytical method #99

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Product Name

2-Methoxy-1-propanol

2-Methoxy-1-propanol Synthetic route

2-Methoxy-1-propanol Chemical Properties

2-Methoxy-1-propanol Uses

2-Methoxy-1-propanol Consensus Reports

2-Methoxy-1-propanol Safety Profile

2-Methoxy-1-propanol Standards and Recommendations

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