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Name	4-Chlorobenzhydrylchloride	EINECS	205-158-6
CAS No.	134-83-8	Density	1.23 g/cm³
PSA	0.00000	LogP	4.66820
Solubility	immiscible with water	Melting Point	N/A
Formula	C₁₃H₁₀Cl₂	Boiling Point	352.7 °C at 760 mmHg
Molecular Weight	237.128	Flash Point	146.9 °C
Transport Information	UN 3265 8/PG 2	Appearance	colorless or Off-yellow liquid
Safety	26-27-36/37/39-45	Risk Codes	34-36/37-36
Molecular Structure		Hazard Symbols	C
Synonyms	Methane,chloro(p-chlorophenyl)phenyl- (6CI,7CI,8CI);4-Chlorobenzhydryl chloride;Chloro(p-chlorophenyl)phenylmethane;NSC 49126;p-Chlorobenzhydryl chloride;Chloro(4-chlorophenyl)phenylmethane;	Article Data	23

4-Chlorobenzhydrylchloride Synthetic route

: 119-56-2
(4-chlorophenyl)phenylmethanol

: 134-83-8
1-chloro-4-(chloro(phenyl)methyl)benzene

Conditions

Conditions	Yield
With hydrogenchloride In ethanol Heating;	95%
With hydrogenchloride; diethyl ether
With hydrogenchloride; benzene

: 134-85-0
4-chlorobenzophenone

: 134-83-8
1-chloro-4-(chloro(phenyl)methyl)benzene

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 90 percent / sodium borohydride 2: 95 percent / hydrochloric acid / ethanol / Heating View Scheme
Multi-step reaction with 2 steps 1: NaBH4 / tetrahydrofuran 2: HCl, CaCl2 / benzene View Scheme
Multi-step reaction with 2 steps 1: NaBH4 / propan-2-ol 2: HCl, Drierite / CH2Cl2 View Scheme

: 831-81-2
4-chlorophenyl(phenyl)methane

: 134-83-8
1-chloro-4-(chloro(phenyl)methyl)benzene

Conditions

Conditions	Yield
With N-chloro-succinimide; 9-(2-mesityl)-10-methylacridinium perchlorate In dichloromethane at 20℃; for 1h; Sealed tube; Inert atmosphere; Irradiation;

: 104-88-1
4-chlorobenzaldehyde

: 134-83-8
1-chloro-4-(chloro(phenyl)methyl)benzene

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: tetrahydrofuran / 1 h / 20 °C 2: SOCl2 / CH2Cl2 / 1 h / 0 °C View Scheme

: phenylmagnesium bromide

isopropyl magnesium halide: isopropyl magnesium halide

: 134-83-8
1-chloro-4-(chloro(phenyl)methyl)benzene

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: tetrahydrofuran / 1 h / 20 °C 2: SOCl2 / CH2Cl2 / 1 h / 0 °C View Scheme

: 7647-01-0
hydrogenchloride

: 119-56-2
(4-chlorophenyl)phenylmethanol

: 71-43-2
benzene

A: 134-83-8
1-chloro-4-(chloro(phenyl)methyl)benzene

B: 7732-18-5
water

Conditions

Conditions	Yield
at 60℃; Equilibrium constant;

: 134-83-8
1-chloro-4-(chloro(phenyl)methyl)benzene

: 134-85-0
4-chlorobenzophenone

Conditions

Conditions	Yield
With N-Bromosuccinimide; water In chloroform for 3h; Time; Reflux;	97%

: 120-43-4
4-ethoxycarbonylpiperazine

: 134-83-8
1-chloro-4-(chloro(phenyl)methyl)benzene

: 80476-89-7
ethyl {4-[(4-chlorophenyl)phenylmethyl]piperazin-1-yl}carboxylate

Conditions

Conditions	Yield
With potassium carbonate In acetonitrile at 20℃; for 24h;	96%

: 134-83-8
1-chloro-4-(chloro(phenyl)methyl)benzene

: (R)-5-Oxo-1-trimethylsilanyl-pyrrolidine-2-carboxylic acid methyl ester

A: 75-77-4
chloro-trimethyl-silane

B: (R)-1-[(4-Chloro-phenyl)-phenyl-methyl]-5-oxo-pyrrolidine-2-carboxylic acid methyl ester

Conditions

Conditions	Yield
With trifluorormethanesulfonic acid at 130℃; for 1.5h;	A n/a B 91%

: 134-83-8
1-chloro-4-(chloro(phenyl)methyl)benzene

: 603-35-0
triphenylphosphine

: 25361-60-8
<(4-chlorophenyl)phenylmethyl>triphenylphosphonium chloride

Conditions

Conditions	Yield
at 160℃; for 6h;	88%

4-Chlorobenzhydrylchloride Chemical Properties

Product Name: 4-Chlorobenzhydrylchloride (CAS NO.134-83-8)

Molecular Formula: C₁₃H₁₀Cl₂
Molecular Weight: 237.13g/mol
Mol File: 134-83-8.mol
EINECS: 205-158-6
Appearance: clear light yellow liquid
Boiling point: 319.6 °C at 760 mmHg
Flash Point: 139.8 °C
Density: 1.23 g/cm³
Refractive index: n20/D 1.603(lit.)
Water Solubility: IMMISCIBLE
Sensitive: Moisture Sensitive
Index of Refraction: 1.593
Molar Refractivity: 65.35 cm³
Molar Volume: 192.7 cm³
Surface Tension: 41.7 dyne/cm
Enthalpy of Vaporization: 53.89 kJ/mol
Vapour Pressure: 0.000626 mmHg at 25°C
XLogP3-AA: 5.1
H-Bond Donor: 0
H-Bond Acceptor: 0
Structure Descriptors of 4-Chlorobenzhydrylchloride (CAS NO.134-83-8):
IUPAC Name: 1-chloro-4-[chloro(phenyl)methyl]benzene
Canonical SMILES: C1=CC=C(C=C1)C(C2=CC=C(C=C2)Cl)Cl
InChI: InChI=1S/C13H10Cl2/c14-12-8-6-11(7-9-12)13(15)10-4-2-1-3-5-10/h1-9,13H
InChIKey: ALKWTKGPKKAZMN-UHFFFAOYSA-N

4-Chlorobenzhydrylchloride Safety Profile

Safety Information of 4-Chlorobenzhydrylchloride (CAS NO.134-83-8):
Hazard Codes: C Corrosive
Risk Statements: 34-36/37-36
R34:Causes burns.
R36/37:Irritating to eyes and respiratory system.
R36:Irritating to eyes.
Safety Statements: 26-27-36/37/39-45
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S27:Take off immediately all contaminated clothing.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
RIDADR: UN 3265 8/PG 2
WGK Germany: 3
HazardClass: 8
PackingGroup: II
HS Code: 29036990

4-Chlorobenzhydrylchloride Specification

4-Chlorobenzhydrylchloride , its CAS NO. is 134-83-8, the synonyms are Chloro(p-chlorophenyl)phenylmethane ; Benzene, 1-chloro-4-(chlorophenylmethyl)- ; Methane, chloro(p-chlorophenyl)phenyl- (8CI) ; alpha,4-Dichloro-alpha-phenyltoluene .

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