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134-83-8

Basic Information
CAS No.: 134-83-8
Name: 4-Chlorobenzhydrylchloride
Article Data: 23
Molecular Structure:
Molecular Structure of 134-83-8 (4-Chlorobenzhydrylchloride)
Formula: C13H10Cl2
Molecular Weight: 237.128
Synonyms: Methane,chloro(p-chlorophenyl)phenyl- (6CI,7CI,8CI);4-Chlorobenzhydryl chloride;Chloro(p-chlorophenyl)phenylmethane;NSC 49126;p-Chlorobenzhydryl chloride;Chloro(4-chlorophenyl)phenylmethane;
EINECS: 205-158-6
Density: 1.23 g/cm3
Boiling Point: 352.7 °C at 760 mmHg
Flash Point: 146.9 °C
Solubility: immiscible with water
Appearance: colorless or Off-yellow liquid
Hazard Symbols: CorrosiveC
Risk Codes: 34-36/37-36
Safety: 26-27-36/37/39-45
Transport Information: UN 3265 8/PG 2
PSA: 0.00000
LogP: 4.66820
Synthetic route
119-56-2

(4-chlorophenyl)phenylmethanol

134-83-8

1-chloro-4-(chloro(phenyl)methyl)benzene

Conditions
ConditionsYield
With hydrogenchloride In ethanol Heating;95%
With hydrogenchloride; diethyl ether
With hydrogenchloride; benzene
134-85-0

4-chlorobenzophenone

134-83-8

1-chloro-4-(chloro(phenyl)methyl)benzene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 90 percent / sodium borohydride
2: 95 percent / hydrochloric acid / ethanol / Heating
View Scheme
Multi-step reaction with 2 steps
1: NaBH4 / tetrahydrofuran
2: HCl, CaCl2 / benzene
View Scheme
Multi-step reaction with 2 steps
1: NaBH4 / propan-2-ol
2: HCl, Drierite / CH2Cl2
View Scheme
831-81-2

4-chlorophenyl(phenyl)methane

134-83-8

1-chloro-4-(chloro(phenyl)methyl)benzene

Conditions
ConditionsYield
With N-chloro-succinimide; 9-(2-mesityl)-10-methylacridinium perchlorate In dichloromethane at 20℃; for 1h; Sealed tube; Inert atmosphere; Irradiation;
104-88-1

4-chlorobenzaldehyde

134-83-8

1-chloro-4-(chloro(phenyl)methyl)benzene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: tetrahydrofuran / 1 h / 20 °C
2: SOCl2 / CH2Cl2 / 1 h / 0 °C
View Scheme

phenylmagnesium bromide

isopropyl magnesium halide

isopropyl magnesium halide

134-83-8

1-chloro-4-(chloro(phenyl)methyl)benzene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: tetrahydrofuran / 1 h / 20 °C
2: SOCl2 / CH2Cl2 / 1 h / 0 °C
View Scheme
7647-01-0

hydrogenchloride

119-56-2

(4-chlorophenyl)phenylmethanol

71-43-2

benzene

A

134-83-8

1-chloro-4-(chloro(phenyl)methyl)benzene

B

7732-18-5

water

Conditions
ConditionsYield
at 60℃; Equilibrium constant;
134-83-8

1-chloro-4-(chloro(phenyl)methyl)benzene

134-85-0

4-chlorobenzophenone

Conditions
ConditionsYield
With N-Bromosuccinimide; water In chloroform for 3h; Time; Reflux;97%
120-43-4

4-ethoxycarbonylpiperazine

134-83-8

1-chloro-4-(chloro(phenyl)methyl)benzene

80476-89-7

ethyl {4-[(4-chlorophenyl)phenylmethyl]piperazin-1-yl}carboxylate

Conditions
ConditionsYield
With potassium carbonate In acetonitrile at 20℃; for 24h;96%
134-83-8

1-chloro-4-(chloro(phenyl)methyl)benzene

(R)-5-Oxo-1-trimethylsilanyl-pyrrolidine-2-carboxylic acid methyl ester

A

75-77-4

chloro-trimethyl-silane

B

(R)-1-[(4-Chloro-phenyl)-phenyl-methyl]-5-oxo-pyrrolidine-2-carboxylic acid methyl ester

Conditions
ConditionsYield
With trifluorormethanesulfonic acid at 130℃; for 1.5h;A n/a
B 91%
134-83-8

1-chloro-4-(chloro(phenyl)methyl)benzene

603-35-0

triphenylphosphine

25361-60-8

<(4-chlorophenyl)phenylmethyl>triphenylphosphonium chloride

Conditions
ConditionsYield
at 160℃; for 6h;88%
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Chemistry

Product Name: 4-Chlorobenzhydrylchloride (CAS NO.134-83-8)

Molecular Formula: C13H10Cl2
Molecular Weight: 237.13g/mol
Mol File: 134-83-8.mol
EINECS: 205-158-6
Appearance: clear light yellow liquid
Boiling point: 319.6 °C at 760 mmHg
Flash Point: 139.8 °C
Density: 1.23 g/cm3
Refractive index: n20/D 1.603(lit.)
Water Solubility: IMMISCIBLE
Sensitive: Moisture Sensitive
Index of Refraction: 1.593 
Molar Refractivity: 65.35 cm3 
Molar Volume: 192.7 cm3 
Surface Tension: 41.7 dyne/cm
Enthalpy of Vaporization: 53.89 kJ/mol
Vapour Pressure: 0.000626 mmHg at 25°C
XLogP3-AA: 5.1
H-Bond Donor: 0
H-Bond Acceptor: 0
Structure Descriptors of 4-Chlorobenzhydrylchloride (CAS NO.134-83-8):
  IUPAC Name: 1-chloro-4-[chloro(phenyl)methyl]benzene
  Canonical SMILES: C1=CC=C(C=C1)C(C2=CC=C(C=C2)Cl)Cl
  InChI: InChI=1S/C13H10Cl2/c14-12-8-6-11(7-9-12)13(15)10-4-2-1-3-5-10/h1-9,13H 
  InChIKey: ALKWTKGPKKAZMN-UHFFFAOYSA-N

Safety Profile

Safety Information of 4-Chlorobenzhydrylchloride (CAS NO.134-83-8):
Hazard Codes: CCorrosive
Risk Statements: 34-36/37-36  
R34:Causes burns. 
R36/37:Irritating to eyes and respiratory system. 
R36:Irritating to eyes.
Safety Statements: 26-27-36/37/39-45
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S27:Take off immediately all contaminated clothing. 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection. 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
RIDADR: UN 3265 8/PG 2
WGK Germany: 3
HazardClass: 8
PackingGroup: II
HS Code: 29036990

Specification

 4-Chlorobenzhydrylchloride , its CAS NO. is 134-83-8, the synonyms are Chloro(p-chlorophenyl)phenylmethane ; Benzene, 1-chloro-4-(chlorophenylmethyl)- ; Methane, chloro(p-chlorophenyl)phenyl- (8CI) ; alpha,4-Dichloro-alpha-phenyltoluene .