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Cas Database |
| Name |
4-Vinylbenzyl glycidyl ether |
EINECS | N/A |
| CAS No. | 113538-80-0 | Density | 1.088g/cm3 |
| PSA | 21.76000 | LogP | 2.24500 |
| Solubility | N/A | Melting Point |
N/A |
| Formula | C12H14O2 | Boiling Point | 299.221 °C at 760 mmHg |
| Molecular Weight | 190.242 | Flash Point | 121.095 °C |
| Transport Information | N/A | Appearance | N/A |
| Safety | Risk Codes | N/A | |
| Molecular Structure |
|
Hazard Symbols | N/A |
| Synonyms |
4-Vinylbenzyl glycidyl ether;2-{[(4-ethenylphenyl)Methoxy]Methyl}oxirane |
Article Data | 14 |
4-Vinylbenzyl glycidyl ether Synthetic route
- 1592-20-7
4-Vinylbenzyl chloride
- 556-52-5
oxiranyl-methanol
- 113538-80-0
2-(4-vinyl-benzyloxymethyl)-oxirane
| Conditions | Yield |
|---|---|
| With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0℃; for 4h; | 86% |
| Stage #1: oxiranyl-methanol With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0℃; Inert atmosphere; Stage #2: 4-Vinylbenzyl chloride In N,N-dimethyl-formamide; mineral oil at 20℃; for 4h; Inert atmosphere; | 86% |
| With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0℃; for 1h; | 85% |
- 292638-84-7
styrene
- 113538-80-0
2-(4-vinyl-benzyloxymethyl)-oxirane
| Conditions | Yield |
|---|---|
| In toluene |
- 2488-01-9
1,4-bis(dimethylsilyl)benzene
- 113538-80-0
2-(4-vinyl-benzyloxymethyl)-oxirane
| Conditions | Yield |
|---|---|
| With platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex In 5,5-dimethyl-1,3-cyclohexadiene at 0 - 20℃; for 3.16667h; Inert atmosphere; | 90% |
- 124-38-9
carbon dioxide
- 113538-80-0
2-(4-vinyl-benzyloxymethyl)-oxirane
| Conditions | Yield |
|---|---|
| With lithium bromide In N,N-dimethyl-formamide at 100℃; for 24h; | 81% |
- 75-15-0
carbon disulfide
- 113538-80-0
2-(4-vinyl-benzyloxymethyl)-oxirane
- 1414436-28-4
4-vinylbenzyl 1,3-oxathiolane-2-thione-5-ylmethyl ether
| Conditions | Yield |
|---|---|
| With lithium bromide In tetrahydrofuran at 0 - 20℃; | 81% |
- 113538-80-0
2-(4-vinyl-benzyloxymethyl)-oxirane
- 114689-61-1
2-(2-(2-(2-(4-vinylbenzyloxy)ethoxy)ethoxy)ethoxy)ethanol
| Conditions | Yield |
|---|---|
| With 2,2’-azobis(4-methoxy-2,4-dimethyl)valeronitrile In chloroform at 45℃; for 48h; | 77% |
| Conditions | Yield |
|---|---|
| With boron trifluoride diethyl etherate In dichloromethane at 0 - 20℃; for 4.5h; | 66% |
| Conditions | Yield |
|---|---|
| With boron trifluoride diethyl etherate In dichloromethane at 0 - 20℃; for 4.5h; | 63% |
- 292638-84-7
styrene
- 113538-80-0
2-(4-vinyl-benzyloxymethyl)-oxirane
- 515881-62-6
tetraethylene glycol mono-2-phenyl-2-propenyl ether
| Conditions | Yield |
|---|---|
| 2,2'-azobis(isobutyronitrile) In chloroform for 48h; Heating / reflux; | 61% |
| Conditions | Yield |
|---|---|
| Stage #1: N-(p-tolyl)glycine With sodium hydroxide In tetrahydrofuran; water at 20℃; for 0.5h; pH=8.7; Stage #2: 2-(4-vinyl-benzyloxymethyl)-oxirane In tetrahydrofuran; water at 20℃; for 48h; | 57% |
4-Vinylbenzyl glycidyl ether Specification
The 4-Vinylbenzyl glycidyl ether, with CAS registry number 113538-80-0, has the systematic name of 2-{[(4-ethenylbenzyl)oxy]methyl}oxirane. Besides this, it is also called oxiran-2-yl[(4-vinylphenyl)methoxy]methane. And the chemical formula of tihs chemical is C12H14O2.
Physical properties of 4-Vinylbenzyl glycidyl ether: (1)ACD/LogP: 2.21; (2)# of Rule of 5 Violations: 0; (3)#H bond acceptors: 2; (4)#H bond donors: 0; (5)#Freely Rotating Bonds: 5; (6)Polar Surface Area: 21.76 Å2; (7)Index of Refraction: 1.569; (8)Molar Refractivity: 57.312 cm3; (9)Molar Volume: 174.867 cm3; (10)Polarizability: 22.72×10-24cm3; (11)Surface Tension: 42.164 dyne/cm; (12)Density: 1.088 g/cm3; (13)Flash Point: 121.095 °C; (14)Enthalpy of Vaporization: 51.763 kJ/mol; (15)Boiling Point: 299.221 °C at 760 mmHg; (16)Vapour Pressure: 0.002 mmHg at 25°C.
You can still convert the following datas into molecular structure:
(1)SMILES: O(Cc1ccc(\C=C)cc1)CC2OC2
(2)InChI: InChI=1/C12H14O2/c1-2-10-3-5-11(6-4-10)7-13-8-12-9-14-12/h2-6,12H,1,7-9H2
(3)InChIKey: ZADXFVHUPXKZBJ-UHFFFAOYAO
(4)Std. InChI: InChI=1S/C12H14O2/c1-2-10-3-5-11(6-4-10)7-13-8-12-9-14-12/h2-6,12H,1,7-9H2
(5)Std. InChIKey: ZADXFVHUPXKZBJ-UHFFFAOYSA-N
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