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18027-10-6

SODIUM TRIMETHYLSILANOLATE is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 18027-10-6 Structure

  • Basic information

    1. Product Name: SODIUM TRIMETHYLSILANOLATE
    2. Synonyms: SodiuM odiuM triMethylsilanolate;SodiuM triMethylsilanolate, 1.0 M solution in THF, J&KSeal;SodiuM triMethylsilanolate 95%;SodiuM triMethylsilanolate, 1.0 M solution in THF, HySeal Spc;SODIUM TRIMETHYLSILANOLATE;TRIMETHYLSILANOL, SODIUM SALT;trimethyl-silanosodiumsalt;SODIUM TRIMETHYLSILANOLATE, 1.0M SOLUTIO N IN DICHLOROMETHANE
    3. CAS NO:18027-10-6
    4. Molecular Formula: C3H9NaOSi
    5. Molecular Weight: 112.18
    6. EINECS: 241-939-8
    7. Product Categories: Chemical Synthesis;Organic Bases;Synthetic Reagents
    8. Mol File: 18027-10-6.mol

  • Chemical Properties

    1. Melting Point: 230 °C (dec.)(lit.)
    2. Boiling Point: 75 °C at 760 mmHg
    3. Flash Point: −2 °F
    4. Appearance: /
    5. Density: 1.283 g/mL at 25 °C
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. BRN: 3912148
    10. CAS DataBase Reference: SODIUM TRIMETHYLSILANOLATE(CAS DataBase Reference)
    11. NIST Chemistry Reference: SODIUM TRIMETHYLSILANOLATE(18027-10-6)
    12. EPA Substance Registry System: SODIUM TRIMETHYLSILANOLATE(18027-10-6)

  • Safety Data

    1. Hazard Codes: T,C,F
    2. Statements: 34-40-23/24/25-20/21/22-19-11-37
    3. Safety Statements: 26-36/37/39-45-28-27-16
    4. RIDADR: UN 3267 8/PG 2
    5. WGK Germany: 3
    6. RTECS:
    7. F: 3-10-21
    8. TSCA: Yes
    9. HazardClass: 8
    10. PackingGroup: III
    11. Hazardous Substances Data: 18027-10-6(Hazardous Substances Data)

18027-10-6 Usage

Purification Methods

It is very soluble in Et2O and *C6H6 but moderately soluble in pet ether. It is purified by sublimation at 130-150o in a high vacuum. [Hyde et al. J Am Chem Soc 75 5615 1953, Tatlock & Rochow J Org Chem 17 1555 1952, Beilstein 4 III 1856.]

Check Digit Verification of cas no

The CAS Registry Mumber 18027-10-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,8,0,2 and 7 respectively; the second part has 2 digits, 1 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 18027-10:
(7*1)+(6*8)+(5*0)+(4*2)+(3*7)+(2*1)+(1*0)=86
86 % 10 = 6
So 18027-10-6 is a valid CAS Registry Number.
InChI:InChI=1/C3H10OSi.Na/c1-5(2,3)4;/h4H,1-3H3;/q;+1

18027-10-6 Well-known Company Product Price

  • Brand
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  • CAS number
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  • Detail

  • Aldrich

  • (329576)  Sodiumtrimethylsilanolate  95%

  • 18027-10-6

  • 329576-25G

  • 1,396.98CNY

  • Detail

  • Aldrich

  • (329576)  Sodiumtrimethylsilanolate  95%

  • 18027-10-6

  • 329576-100G

  • 4,248.27CNY

  • Detail

18027-10-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name SODIUM TRIMETHYLSILANOLATE

1.2 Other means of identification

Product number -
Other names Trimethyl(sodiooxy)silane

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:18027-10-6 SDS

18027-10-6Relevant articles and documents

HETEROBICYCLIC SPHINGOSINE 1-PHOSPHATE ANALOGS

-

Page/Page column 23, (2010/05/14)

Compounds that have agonist activity at one or more of the SlP receptors are provided. The compounds are sphingosine analogs that, after phosphorylation, can behave as agonists at SlP receptors.

Scope and limitations of sodium and potassium trimethylsilanolate as reagents for conversion of esters to carboxylic acids

Lovric, Marija,Cepanec, Ivica,Litvic, Mladen,Bartolincic, Anamarija,Vinkovic, Vladimir

, p. 109 - 115 (2008/02/04)

Sodium or potassium trimethylsilanolate act as versatile and very powerful reagents for conversion of a wide variety of esters to carboxylic acids. The reactions were performed in tetrahydrofuran under mild reaction conditions with high to quantitative yields.

Monosodiumoxyorganoalkoxysilanes: Synthesis and properties

Rebrov,Muzafarov

, p. 514 - 541 (2007/10/03)

The reaction of organoalkoxysilanes with sodium hydroxide was studied in detail. Studies indicate that this reaction involves more than one stage and involves rather complex multistep process, which leads to the formation of both monosodiumoxyorganoalkoxysilanes (MSOAS) and several secondary products. Analysis of experimental evidence makes it possible to advance the mechanism behind this phenomenon and to define the optimum conditions for the preparation of pure MSOAS with high yields. Different MSOAS were synthesized and their basic physicochemical properties were studied. MSOAS are shown to constitute multifunctional reagents with chemically independent functional groups, and their reaction with trimethylchlorosilane selectively proceeds via - ONa groups, whereas their interaction with triethylesilanol and higher alcohols proceeds exclusively via - OAlk groups. Exchange interaction between MSOAS and organoalkoxysilanes via - ONa and - OAlk groups was found and studied in detail. Temperature corresponding to the onset of thermal degradation of MSOAS was estimated to be equal to ～ 180-190°C.

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