104330-36-1Relevant articles and documents
A highly efficient and convenient method for the direct conversion of alkyl THP ethers into the corresponding alkyl benzyl ethers
Suzuki, Takeshi,Ohashi, Kousaburo,Oriyama, Takeshi
, p. 1561 - 1563 (1999)
Direct conversion of alcohol tetrahydropyranyl (THP) ethers into the corresponding benzyl ethers can be conveniently performed by reaction with triethylsilane and benzaldehyde in the presence of a catalytic amount of trimethylsilyl trifluoromethanesulfona
Development of a Storable Triazinone-Based Reagent for O- p-Methoxybenzylation under Mild Heating Conditions
Fujita, Hikaru,Terasaki, Hiromitsu,Kakuyama, Satoshi,Hioki, Kazuhito,Kunishima, Munetaka
, (2019)
A new triazinone-based reagent for O-p-methoxybenzylation has been developed. In spite of its stability in solid form, this reagent converts a free alcohol into the corresponding p-methoxybenzyl ether with mild heating (50-60 °C) in a solution. High funct
p-Methylbenzyl 2,2,2-Trichloroacetimidate: Simple Preparation and Application to Alcohol Protection
Arai, Tomoki,Ikeuchi, Kazutada,Murasawa, Kentaro,Yamada, Hidetsohi
supporting information, p. 1034 - 1037 (2020/09/16)
A method for p-methylbenzyl (MBn) protection of alcohols by using MBn 2,2,2-trichloroacetimidate is described. The trichloroacetimidate can easily be prepared and isolated as a stable white powder without purification by silica gel chromatography. Catalytic use of zinc(II) triflate in diethyl ether activates the trichloroacetimidate to enable MBn protection of various alcohols.
Simple and rapid p-methoxybenzylation of hydroxy and amide groups at room temperature by NaOt-Bu and DMSO
Hamada, Shohei,Sugimoto, Koichi,Iida, Masashi,Furuta, Takumi
supporting information, (2019/11/13)
The p-methoxybenzylation of hydroxy and amide groups by p-methoxybenzyl chloride utilizing NaOt-Bu in DMSO is described. p-Methoxybenzylation of sterically hindered menthol using NaOt-Bu in DMSO proceeded faster than the commonly used methods which use Na