- General procedures for the purification of Aldehydes
-
Common impurities found in aldehydes are the corresponding alcohols, aldols and from self-condensation, and the corresponding acids formed by autoxidation. Acids can be removed by shaking with aqueous 10% sodium bicarbonate solution. The organic liquid is then washed with water. It is dried with anhydrous sodium sulfate or magnesium sulfate and then fractionally distilled. Water soluble aldehydes must be dissolved in a suitable solvent such as diethyl ether before being washed in this way. Further purification can be effected via the bisulfite derivative or the Schiff base formed with aniline or benzidine. Solid aldehydes can be dissolved in diethyl ether and purified as above. Alternatively, they can be steam distilled, then sublimed and crystallised from toluene or petroleum ether.
Prev:No record
Next:No record - 【Back】【Close 】【Print】【Add to favorite 】
- Related information
- Preparation of 4-Oxo-4-(3-Pyridyl)butyronitrile: Cyanide-catalyzed Conjugate Addition of Aryl Aldehydes
- Strecker Amino Acid Synthesis
- Stephen Aldehyde Synthesis
- Sommelet Reaction
- Reimer-Tiemann Reaction
- Meyers Aldehyde Synthesis
- Janovsky Reaction
- Gattermann Aldehyde Synthesis
- Bodroux-Chichibabin Aldehyde Synthesis
-
Health and Chemical more >
-
Hot Products
- 115-24-2 SULFONAL
- 122111-03-9 Gemcitabine hydrochloride
- 320418-32-4 5-(carboxymethyl)-1-(2,4-dichlorophenyl)-1H-1,2,3-triazole-4-carboxylic acid
- 124-68-5 1-Propanol,2-amino-2-methyl-
- 68439-72-5 Catafor O-5
- 22362-15-8 4-benzylsulfanylmethyl-6-morpholin-4-yl-[1,3,5]triazin-2-ylamine
- 64742-96-7 Solvent naphtha (petroleum), heavy aliph.
- 54971-26-5 2-BROMOHEXANOYL BROMIDE
- 9014-63-5 Xylan
- 25728-82-9 Octacosanoic acid,sodium salt
- 1313-97-9 Neodymium oxide
- 91273-04-0 N,N-Bis(2-ethylhexyl)-[(1,2,4-triazol-1-yl)methyl]amin


