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| CAS No.: | 675-14-9 |
|---|---|
| Name: | Cyanuric fluoride |
| Molecular Structure: | |
|
|
|
| Formula: | C3F3 N3 |
| Molecular Weight: | 135.048 |
| Synonyms: | Cyanuricfluoride (6CI); s-Triazine, 2,4,6-trifluoro- (7CI,8CI);1,3,5-Trifluoro-2,4,6-triazine; 2,4,6-Trifluoro-1,3,5-triazine; 2,4,6-Trifluoro-s-triazine;2,4,6-Trifluoro-sym-triazine; 2,4,6-Trifluorotriazine; Cyanuric trifluoride;NSC 168386; Trifluoro-1,3,5-triazine; Trifluoro-s-triazine |
| EINECS: | 211-620-8 |
| Density: | 1.652 g/cm3 |
| Melting Point: | -38ºC |
| Boiling Point: | 316.1 °C at 760 mmHg |
| Flash Point: | 145 °C |
| Appearance: | amber liquid |
| Hazard Symbols: |
 
|
| Risk Codes: | R24;R26;R35 |
| Safety: | Poison by skin contact and inhalation. Questionable carcinogen with experimental carcinogenic data. When heated to decomposition it emits very toxic fumes of F− and NOx. See also FLUORIDES. |
| Transport Information: | UN 3389 |
| PSA: | 38.67000 |
| LogP: | 0.28890 |
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- 894852-01-87-BROMO-2,2-DIMETHYL-2H-PYRIDO[3,2-B][1,4]OXAZIN-3(4H)-ONE
| Conditions | Yield |
|---|---|
| With sulfolane; sodium fluoride at 150℃; Reagent/catalyst; Large scale; | 97% |
| With tetrabutyl ammonium fluoride In dimethyl sulfoxide at 60℃; for 6h; Temperature; Solvent; | 95% |
| With 1-methyl-pyrrolidin-2-one; hydrogen fluoride; triethylamine at 20 - 25℃; for 0.5h; | 90% |
- 108-77-0
1,3,5-trichloro-2,4,6-triazine
- 7783-56-4
antimony(III) fluoride
- 675-14-9
trifluoro-[1,3,5]triazine
| Conditions | Yield |
|---|---|
| With antimony(III) chloride; chlorine 160-180°C, 10 mol SbF3, 1 mol SbCl3, 3 mol Cl2; | 91% |
| With antimony(III) chloride; chlorine 160-180°C, 10 mol SbF3, 1 mol SbCl3, 3 mol Cl2; | 91% |
| With chlorine at 100°C, exclusion of H2O; destillation; | 71.4% |
- 57310-43-7
4-N,N-dichloroamino-2,3,5,6-tetrafluoropyridine
A
- 675-14-9
trifluoro-[1,3,5]triazine
B
- 52026-98-9
4-chloro-2,3,5,6-tetrafluoropyridine
C
- 700-16-3
Pentafluoropyridine
D
- 75-69-4
trichlorofluoromethane
E
- 667-42-5
2-chloro-3,3-difluoro-acrylonitrile
F
- 13177-77-0
tetrafluoropyrazine
| Conditions | Yield |
|---|---|
| at 550℃; under 2 Torr; Mechanism; vacuum pyrolysis, other fluoropyridine compounds; | A n/a B 75% C n/a D n/a E n/a F n/a |
- 112291-51-7
1,2,3-trifluoro-4,5,6-triazine
- 112291-50-6
perfluoro-4,6-di-isopropyl-1,2,3-triazine
A
- 675-14-9
trifluoro-[1,3,5]triazine
B
- 20017-47-4
perfluoro-2,4-di-isopropylpyridine
C
- 129574-48-7
perfluoro-2,4,6,8-tetraisopropyl-1,5-diazatricyclo<4.2.0.02,5>octa-3,7-diene
| Conditions | Yield |
|---|---|
| In 1,1,2-Trichloro-1,2,2-trifluoroethane for 24h; Irradiation; | A 0.01 g B 53% C 11% |
| In 1,1,2-Trichloro-1,2,2-trifluoroethane for 24h; Irradiation; | A 0.01 g B 4% C 11 g |
| In 1,1,2-Trichloro-1,2,2-trifluoroethane for 24h; Mechanism; Irradiation; | A 0.01 g B 0.17 g C 0.03 g |
- 108-77-0
1,3,5-trichloro-2,4,6-triazine
A
- 675-14-9
trifluoro-[1,3,5]triazine
B
- 696-85-5
2-chloro-4,6-difluoro-[1,3,5]triazine
C
- 696-84-4
2,4-dichloro-6-fluoro-[1,3,5]triazine
| Conditions | Yield |
|---|---|
| With potassium fluoride at 300℃; for 2h; Product distribution; C3Cl3N3/KF = 16 x 10 E-2, other temperatures, other times, other molar ratios; | A n/a B n/a C 48% |
| With cesium fluoride; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate at 80℃; |
- 108-77-0
1,3,5-trichloro-2,4,6-triazine
- 7783-60-0
sulfur tetrafluoride
- 675-14-9
trifluoro-[1,3,5]triazine
| Conditions | Yield |
|---|---|
| in 1:6 molar ratio, at 250°C, in autoclave; | 40% |
- 7783-54-2
nitrogen trifluoride
- 506-77-4
cyanogen chloride
A
- 675-14-9
trifluoro-[1,3,5]triazine
B
- 73513-59-4
cis-hexafluoroazomethane
C
- 371-71-1
Perfluoro-2-azapropen
| Conditions | Yield |
|---|---|
| In not given at 500°C, in Ni-tube, in excess of NF3; | A 40% B 30% C 30% |
| Conditions | Yield |
|---|---|
| at 500℃; for 42h; | A 32% B 12% C n/a |
- 108-77-0
1,3,5-trichloro-2,4,6-triazine
A
- 675-14-9
trifluoro-[1,3,5]triazine
B
- 696-85-5
2-chloro-4,6-difluoro-[1,3,5]triazine
| Conditions | Yield |
|---|---|
| With antimonypentachloride; antimony(III) fluoride | |
| With antimonypentachloride; antimony(III) fluoride melting, heating, 1 h distn.; fractionated distn.; | |
| With SbF3; SbCl5 melting, heating, 1 h distn.; fractionated distn.; |
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Chemistry
Chemical Name: Cyanuric fluoride
IUPAC NAME: 2,4,6-trifluoro-1,3,5-triazine
CAS No.: 675-14-9
EINECS: 211-620-8
RTECS: XZ1750000
Molecular Formula: C3F3N3
Molecular Weight: 135.05 g/mol
Hazard Note: Corrosive/Toxic
Density: 1.652 g/cm3
Melting Point: -38°C
Flash Point: 145 °C
Boiling Point: 316.1 °C at 760 mmHg
2,4,6-TRIFLUORO-s-TRIAZINE(675-14-9) is a colourless, pungent liquid. it is moisture sensitive and incompatible with xoidizing agents.Following is the structure:
The chemical synonymous of 2,4,6-TRIFLUORO-s-TRIAZINE(675-14-9) are 2,4,6-TRIFLUORO-1,3,5-TRIAZINE;CYANURIC FLUORIDE;1,3,5-triazine,2,4,6-trifluoro-;2,4,6-trifluoro-s-triazin;2,4,6-Trifluoro-s-triazine;2,4,6-Trifluorotriazine;2,4,6-trifluro-s-triazin;5-triazine,2,4,6-trifluoro-3.
Uses
2,4,6-TRIFLUORO-s-TRIAZINE(675-14-9) is mainly used for preparation of reactive dyes and used in organic synthesis.It has been used as a precursor for fibre-reactive dyes, as a specific reagent for tyrosine residues in enzymes, and as a fluorinating agent.
Production
Product Categories about 2,4,6-TRIFLUORO-s-TRIAZINE(675-14-9) is mainly refer to Heterocycles.
Toxicity Data With Reference
| rabbit | LD50 | skin | 160mg/kg (160mg/kg) | SENSE ORGANS AND SPECIAL SENSES: LACRIMATION: EYE LUNGS, THORAX, OR RESPIRATION: BRONCHIOLAR CONSTRICTION | American Industrial Hygiene Association Journal. Vol. 33, Pg. 382, 1972. |
| rat | LC50 | inhalation | 3100ppb/4H (3.1ppm) | BEHAVIORAL: EXCITEMENT LUNGS, THORAX, OR RESPIRATION: CHRONIC PULMONARY EDEMA LUNGS, THORAX, OR RESPIRATION: DYSPNEA | American Industrial Hygiene Association Journal. Vol. 33, Pg. 382, 1972. |
Consensus Reports
Safety Profile
Poison by skin contact and inhalation. Questionable carcinogen with experimental carcinogenic data. When heated to decomposition it emits very toxic fumes of F− and NOx. See also FLUORIDES.
Hazard Codes:
T+: Very toxic 
T: Toxic
C: Corrosive 
Risk Statements about 2,4,6-TRIFLUORO-s-TRIAZINE(675-14-9):
R24 Toxic in contact with skin.
R26 Very toxic by inhalation.
R35 Causes severe burns.
Safety Statements about 2,4,6-TRIFLUORO-s-TRIAZINE(675-14-9):
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S28 After contact with skin, wash immediately with plenty of soap-suds.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
Specification
1. Storage: Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.
2. Handling: All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.
3. Personal Protection: Chemical splash goggles in compliance with OSHA regulations are advised; however, OSHA regulations also permit other type safety glasses. Whre chemical resistant gloves. To prevent repeated or prolonged skin contact, wear impervious clothing and boots.
4. Fire Fighting: Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use agent most appropriate to extinguish fire.
5. Reactivity Profile Inorganic oxidizing agents can react with reducing agents to generate heat and products that may be gaseous (causing pressurization of closed containers). The products may themselves be capable of further reactions (such as combustion in the air). The chemical reduction of materials in this group can be rapid or even explosive, but often requires initiation (heat, spark, catalyst, addition of a solvent). Explosive mixtures of inorganic oxidizing agents with reducing agents often persist unchanged for long periods if initiation is prevented. Such systems are typically mixtures of solids, but may involve any combination of physical states. Some inorganic oxidizing agents are salts of metals that are soluble in water; dissolution dilutes but does not nullify the oxidizing power of such materials. Organic compounds, in general, have some reducing power and can in principle react with compounds in this class. Actual reactivity varies greatly with the identity of the organic compound. Inorganic oxidizing agents can react violently with active metals, cyanides, esters, and thiocyanates. Explosives often consist of an inorganic oxidizing agent mixed in intimate contact with a reducing agent. Gunpowder is such a mixture. Other examples are a mixture of sugar (an organic compound) plus sodium chlorate and magnesium (an inorganic reducing agent) plus barium peroxide. Compounds that inherently contain a group that is a reducing agent and an oxidizing agent are classed in both Group 44 (Inorganic Oxidizing Agents) and in Group 45 (Inorganic Reducing Agents; for example, ammonium nitrate). The strongly oxidizing elements oxygen and fluorine are classified here. Inorganic oxidizing agents that are also acids (such as nitric and perchloric acids) are not included in this group. They are in Group 2 (Acids, Inorganic Oxidizing).