Total synthesis of the proposed structure of macrocaffrine

DOI: 10.1016/j.tet.2007.10.005

Source and publish data:

Tetrahedron p. 12689 - 12694 (2007)

Update date:2022-07-29

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Authors:

Ohba, Masashi

Natsutani, Itaru

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Article abstract of DOI:10.1016/j.tet.2007.10.005

A full account of the total synthesis of 18-demethyl-19-hydroxy-N_a-demethyl-N_b-methylsuaveoline (1), the structure assigned to macrocaffrine isolated from Rauwolfia caffra, is presented. The key steps involved are an intramolecular c

Full text of DOI:10.1016/j.tet.2007.10.005

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