Synthesis of functionalized furans via gold(I)-catalyzed Claisen-type rearrangement

DOI: 10.1021/jo7022685

Source and publish data:

Journal of Organic Chemistry p. 730 - 733 (2008)

Update date:2022-08-05

Topics:

Authors:

Istrate, Florin M.

Gagosz, Fabien L.

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Article abstract of DOI:10.1021/jo7022685

(Chemical Equation Presented) Gold(I)-catalyzed cyclization of pentenynyl allyl ethers allows the rapid construction of functionalized furans. The concerted oxy-Claisen-type mechanism induces a complete selectivity of the process and allows the easy forma

Full text of DOI:10.1021/jo7022685

Synthesis of Functionalized Furans via

Gold(I)-Catalyzed Claisen-Type Rearrangement

Florin M. Istrate and Fabien L. Gagosz*

Laboratoire de Synthe`se Organique, UMR 7652/Ecole

Polytechnique, Ecole Polytechnique, 91128 Palaiseau, France

gagosz@dcso.polytechnique.fr

ReceiVed October 22, 2007

This paper was withdrawn on February 29, 2008.

JO7022685

Published on Web 00/00/0000

730

J. Org. Chem. 2008, 73, 730

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