Journal of Organic Chemistry p. 1000 - 1002 (1986)
Update date:2022-08-02
Topics:
Chou, Ta-shue
Tso, Hsi-Hwa
Lin, Lung Ching
3-Sulfolene 2-anion and 3-methyl-3-sulfolene 2-anion have been generated at -105 deg C and are stable in the absence of electrophiles for at least 15 min at this temperature.These anions were used in sequential reactions with acyl chlorides and alkyl halides to yield the corresponding 2-acyl-2-alkyl-3-sulfolenes.
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