Study on fluorination of 2,3-dideoxy-2,3-(N-tosylepimino)-α-D-allopyranosides, and synthesis of 3'-deoxy-3'-fluoro-kanamycin B and 3',4'-dideoxy-3'-fluorokanamycin B

DOI: 10.1016/S0008-6215(00)90515-9

Source and publish data:

Carbohydrate Research p. 89 - 105 (1992)

Update date:2022-08-05

Topics:

Authors:

Kobayashi

Tsuchiya

Ohgi Ohgi

Taneichi

Koyama Koyama

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Article abstract of DOI:10.1016/S0008-6215(00)90515-9

Reaction of the structurally rigid methyl 2,3-dideoxy-4,6-O-isopropylidene-2,3-(N-tosylepimino)-α-D-allopyrano side (6) with KHF₂ in DMF at 150° gave initially methyl 2,3-dideoxy-2-fluoro-4,6-O-isopropylidene-3-tosylamido-α-D-altropyra noside (

Full text of DOI:10.1016/S0008-6215(00)90515-9

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