Journal of the Chemical Society. Perkin transactions I p. 553 - 557 (1989)
Update date:2022-09-26
Topics:
Barluenga, Jose
Foubelo, Francisco
Fananas, Francisco J.
Yus, Miguel
N-Phenyl or N-benzoyl 2-halogenoallylamines (5) or (10) react successively with phenyl-lithium and lithium naphthalenide at -78 deg C to give the intermediates (4) or (11), which on reaction with electrophiles (water, deuterium oxide, dimethyl disulphide, aldehydes, ketones, or allyl bromide) yield functionalized allyl amines (6) and (12).The corresponding N-alkyl derivatives (9) afford prop-2-ynylamines (8) under the same reaction conditions.
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