Organic Letters p. 5469 - 5472 (2007)
Update date:2022-08-04
Topics:
Pav, Ondroslash
Barvik, Ivan
Budesinsky, Milos
Masojidkova, Milena
Rosenberg, Ivan
Novel seven-membered nucleoside phostones were prepared by the reaction of chlorodiethyl phosphite with 3′,5′-acetals or ketals derived from xylo-dT. A mechanism for the ring enlargement was proposed, and support for it was provided by ab initio calculations.
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(2007)
