Intramolecular 1,3-Dipolar Cycloaddition of Alkyl Azide Enones and Rearrangements of the Triazoline Interemediates. Formal Total Synthesis of (+/-)-Desamylperhydrohistrionicotoxin

DOI: 10.1021/jo00359a019

Source and publish data:

Journal of Organic Chemistry p. 1490 - 1494 (1986)

Update date:2022-07-30

Topics:

Authors:

Sha, Chin-Kang

Ouyang, Sheng-Lian

Hsieh, Der-Yung

Chang, Ruei-Chih

Chang, Shang-Chia

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Article abstract of DOI:10.1021/jo00359a019

Azido enones 8,18,25,39, and 45, which were prepared by the treatment of the corresponding bromide 7, methanesulfonate 17, chloride 24, bromide 38, and toluenesulfonate 44 with sodium azide, were found to undergo intramolecular 1,3-dipolar cycloaddition r

Full text of DOI:10.1021/jo00359a019

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