Intramolecular 1,3-Dipolar Cycloaddition of Alkyl Azide Enones and Rearrangements of the Triazoline Interemediates. Formal Total Synthesis of (+/-)-Desamylperhydrohistrionicotoxin

DOI: 10.1021/jo00359a019

Source and publish data:

Journal of Organic Chemistry p. 1490 - 1494 (1986)

Update date:2022-07-30

Topics:

Authors:

Sha, Chin-Kang

Ouyang, Sheng-Lian

Hsieh, Der-Yung

Chang, Ruei-Chih

Chang, Shang-Chia

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00359a019

Azido enones 8,18,25,39, and 45, which were prepared by the treatment of the corresponding bromide 7, methanesulfonate 17, chloride 24, bromide 38, and toluenesulfonate 44 with sodium azide, were found to undergo intramolecular 1,3-dipolar cycloaddition r

Full text of DOI:10.1021/jo00359a019

Products guided by the article

Product name:3-(4-azidobutyl)-2-butylcyclohex-2-en-1-one

Cas No:100466-73-7

R&D Labs maybe for 100466-73-7

Laizhou City Laiyu Chemical CO.,Ltd

Contact:+86-535-2719337/2719339

Address:Chenggang road zhuyou laizhou City Shangdong China
Shenzhen Sungening Medicine Co., Ltd

Contact:+86-871-65110906

Address:Room702, Building 2, 365 Dianchi Road, Kunming, Yunnan Province, P.R. China
Lanling Hongchuang Flame Retardant Co., Ltd.

Contact:+86-531-68858132

Address:East Huafeichang Road, Cangshan County, Linyi, Shandong, China (Mainland)
Tianjin Bright Future Technology Co., Ltd

Contact:0086-22-58016666

Address:NO.136 DongTeng Lake Street Tianjin Economic and Technology Development Area,Tainjin,China
Fujian Wanke Pharmaceutical Co., LTD.

Contact:+86-598-5026002

Address:Economic development zone,jiangle county

Relevant to this article

Lithium-Catalyzed anti-Markovnikov Intermolecular Hydroamination Reactions of Vinylarenes and Simple Secondary Amines

Doi:10.1002/cctc.201700043
(2017)
New paracyclophane phosphine for highly enantioselective ruthenium-catalyzed hydrogenation of prochiral ketones

Doi:10.1055/s-2007-990917
(2007)
N-hetaryl-2-cyanoacetamides in the synthesis of substituted (E)-N-hetaryl-2-cyanoacrylamides, (E)-N-alkyl-N-hetaryl-2-cyanoacrylamides, and 6-amino-2-oxo-4-phenyl-1-(pyridin-2-yl)-1,2-dihydropyridine-3,5-dicarbonitriles

Doi:10.1134/S1070428007010101
(2007)
Doi:10.1021/ja01471a021
(1961)
Samarium(II) - mediated linker cleavage - cyclization in fluorous synthesis: Reactions of samarium enolates

Doi:10.1021/ol800070y
(2008)
Heterogeneous copper catalyst for the cycloaddition of azides and alkynes without additives under ambient conditions

Doi:10.1021/ol702790w
(2008)

Article Doi