Preparation of α-Substituted S-Phenyl Thio Esters from Aldehydes and (Phenylthio)nitromethane

DOI: 10.1021/jo00357a012

Source and publish data:

Journal of Organic Chemistry p. 1012 - 1015 (1986)

Update date:2022-08-03

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Authors:

Barrett, Anthony G. M.

Graboski, Gregory, G.

Russell, Mark A.

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Article abstract of DOI:10.1021/jo00357a012

Acetaldehyde and isobutyraldehyde, RCHO, reacted with (phenylthio)nitromethane (KO-t-Bu, THF, t-BuOH) followed by methanesulfonyl chloride (Et3N, CH2Cl2) to give the (Z)-alkenes RCH=C(SPh)NO2.These reacted with the nucleophiles View More

Full text of DOI:10.1021/jo00357a012

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