Studies on the Synthesis of Side-Chain Hydroxylated Metabolites of Vitamin D. 2. Stereocontrolled Synthesis of 25-Hydroxyvitamin D2

DOI: 10.1021/jo00358a018

Source and publish data:

Journal of Organic Chemistry p. 1264 - 1269 (1986)

Update date:2022-07-30

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Authors:

Sardina, F. Javier

Mourino, Antonio

Castedo, Luis

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Article abstract of DOI:10.1021/jo00358a018

An efficient synthesis of 25-hydroxyvitamin D2 is described.The chiral center at C-24 was introduced by the stereospecific and regioselective displacement of an allylic carbamate by a cuprate.The triene system was assembled by Horner-Wittig coupling of ke

Full text of DOI:10.1021/jo00358a018

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