METALLORGANISCHE LEWISSAEUREN XX. REAKTIONEN VON (?-C5H5)(CO)2LM-X (L = CO, PR3; M = Mo, W; X = BF4, PF6, AsF6, SbF6) MIT SCHWEFEL-HALTIGEN LIGANDEN

DOI: 10.1016/0022-328X(85)87296-X

Source and publish data:

Journal of Organometallic Chemistry p. 329 - 340 (1985)

Update date:2022-08-03

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Authors:

Urban, Guenter

Suenkel, Karlheinz

Beck, Wolfgang

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Article abstract of DOI:10.1016/0022-328X(85)87296-X

The compounds (?-C5H5)(CO)2LM-X (L = CO, PR3; M = Mo, W; X = BF4, PF6, AsF6, SbF6) react with H2S, p-MeC6H4SH, Ph2S and Ph2SO(L') to give ionic complexes <(?-C5H5)(CO)2LML'>⁺ X^-.Also sulfur-bridged complexes, <(?-C5H5)(CO)3W-SH-W(CO)

Full text of DOI:10.1016/0022-328X(85)87296-X

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