A new class of oxygen nucleophiles for regioselective 1,4-addition to butadiene monoxide catalyzed by palladium complexes

DOI: 10.1016/S0040-4039(97)00550-9

Source and publish data:

Tetrahedron Letters p. 3081 - 3084 (1997)

Update date:2022-07-30

Topics:

Authors:

Bianchi, Daniele

Querci, Cecilia

Ricci, Marco

Santi, Roberto

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Article abstract of DOI:10.1016/S0040-4039(97)00550-9

Butadiene monoxide reacts with high regioselectively with anhydrides to give preferentially diesters of 2 buten-1,4-diol in presence of palladium phosphine complexes. Reaction regioselectivity is strongly influenced by the nature of palladium ligand, anhydride and solvent.

Full text of DOI:10.1016/S0040-4039(97)00550-9

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