Unusual Hydrogen Transfer Pathways in a Re-Pt Heterobimetallic System

DOI: 10.1039/c39850001314

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1314 - 1316 (1985)

Update date:2022-07-29

Topics:

Authors:

Powell, John

Sawyer, Jeffery F.

Stainer, Matthew V. R.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39850001314

The cation cis-(1+) (1+) to Pt(C2H4)(PPh3)2; cp=cyclopentadienyl, cy=cyclohexyl> undergoes a base-catalysed proton transfer accompanied by CO loss to give a terminal rhenium-hydrido cation as the kinetically formed product, which, in the presence of halide ions (other than F(1-)) isomerizes to the thermodynamically preferred product (1+).

Full text of DOI:10.1039/c39850001314

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:{(η5-Cp)(CO)(ON)Re(μ-PCy2)PtHCl(PPh3)}

Cas No:101307-86-2

R&D Labs maybe for 101307-86-2

Changsha Easchem Co.,Limited

website:http://www.easchem.com

Contact:+86-731-89722861 89722891

Address:2/F-4/Bld Colorful Palace, No.605 Changsha Ave, Yuhua Area Changsha Hunan China.
Nanjing Habo Medical Technology Co., Ltd.

Contact:025－85769882

Address:No.108. Ganjiabian east. Qixia District .Nanjing
Tianjin Chemsyntech Chemical Co., Ltd

Contact:+86-22-60872258

Address:Haitai green industry base in Tianjin, K1,5-601
HANGZHOU ICH BIOFARM CO.,LTD

Contact:+86-571-28186845

Address:Room 1224,Eastcom Mansion,398 Wensan Road,Hangzhou,310013 China
Taizhou Elitechemie MediPharma Technology Co.,Ltd.

Contact:+86-523-86810021

Address:Building G14,NO.1 Avenue,China Medical City, Taizhou, Jiangsu,China

Relevant to this article

Doi:10.1021/jo01065a097
(1961)
A highly efficient total synthesis of (R)-(+)-muscopyridine by intramolecular [4+2] cycloaddition of bisketene

Doi:10.1016/j.tetlet.2007.12.112
(2008)
NOVEL (4+1) FRAGMENT COMBINATION APPROACH TO CHIRAL CYCLOPENTANOIDS FROM TARTARIC ACID

Doi:10.1016/S0040-4039(00)98634-9
(1985)
Tunable blue-emitting fluorophores-benzo[1,2-b:4,3-b′]dithiophene and trithia[5]helicene end-capped with electron-rich or electron-deficient aryl substituents

Doi:10.1016/j.tet.2007.12.029
(2008)
Photochemical Formation and Some Chemical Properties of 2,6-Diazabicyclo<2.2.0>hexane-3,5-diones from Pyrimidinium-4-olates. A New Approach to Novel Bis(β-lactans)

Doi:10.1039/c39860000687
(1986)
Doi:10.1039/jr9500000978
(1950)

Article Doi