Unusual Hydrogen Transfer Pathways in a Re-Pt Heterobimetallic System

DOI: 10.1039/c39850001314

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1314 - 1316 (1985)

Update date:2022-07-29

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Authors:

Powell, John

Sawyer, Jeffery F.

Stainer, Matthew V. R.

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Article abstract of DOI:10.1039/c39850001314

The cation cis-(1+) (1+) to Pt(C2H4)(PPh3)2; cp=cyclopentadienyl, cy=cyclohexyl> undergoes a base-catalysed proton transfer accompanied by CO loss to give a terminal rhenium-hydrido cation as the kinetically formed product, which, in the presence of halide ions (other than F(1-)) isomerizes to the thermodynamically preferred product (1+).

Full text of DOI:10.1039/c39850001314

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