Nucleophilic Substitution of Tricoordinate Sulfur Atom of Sulfonium Salt with Retention of Configuration. Different Stereochemistry of Substitution by Amidate Anions

Article abstract of DOI:10.1246/bcsj.58.1934

Optically active N-substituted S-(o-methoxyphenyl)-S-phenylsulfilimines were obtained in moderate yields upon simple treatment of a mixture of o-methoxyphenyl phenyl sulfide and t-butyl hypochlorite in the presence of l-menthol and followed by amidate ani