TRIMETHYLCHOLOROSILANE INDUCED RING OPENING OF 2-ALKYLOXAZOLIDINES TO ENAMINE DERIVATIVES

DOI: 10.1016/S0040-4039(00)95022-6

Source and publish data:

Tetrahedron Letters p. 5303 - 5306 (1985)

Update date:2022-08-05

Topics:

Authors:

Ito, Yoshihiko

Sawamura, Masaya

Kominami, Kazuhiko

Saegusa, Takeo

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Article abstract of DOI:10.1016/S0040-4039(00)95022-6

2-Alkyloxazolidines (5) were ring-opened by trimethylchlorosilane with N,N-diisopropylamine to give N-<2-(trimethylsilyloxy)alkyl>-enamines (6).A MgCl2 promoted Michael reaction of chiral enamines thus prepared was achieved with asymmetric induction.

Full text of DOI:10.1016/S0040-4039(00)95022-6

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