TRIMETHYLCHOLOROSILANE INDUCED RING OPENING OF 2-ALKYLOXAZOLIDINES TO ENAMINE DERIVATIVES

DOI: 10.1016/S0040-4039(00)95022-6

Source and publish data:

Tetrahedron Letters p. 5303 - 5306 (1985)

Update date:2022-08-05

Topics:

Authors:

Ito, Yoshihiko

Sawamura, Masaya

Kominami, Kazuhiko

Saegusa, Takeo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)95022-6

2-Alkyloxazolidines (5) were ring-opened by trimethylchlorosilane with N,N-diisopropylamine to give N-<2-(trimethylsilyloxy)alkyl>-enamines (6).A MgCl2 promoted Michael reaction of chiral enamines thus prepared was achieved with asymmetric induction.

Full text of DOI:10.1016/S0040-4039(00)95022-6

Products guided by the article

Product name:Methyl-[2-methyl-cyclohex-(Z)-ylidenemethyl]-(2-phenyl-1-trimethylsilanyloxymethyl-ethyl)-amine

Cas No:102259-88-1

R&D Labs maybe for 102259-88-1

Lonwin Chemical Group Limited

website:http://www.lonwinchem.com

Contact:Tel: 86-21-59858395

Address:No#966,Huaxu Road,Shanghai 201702,P.R.China
Rudong Zhenfeng Yiyang Chemical Co., Ltd.

Contact:0513-84573047

Address:South Fengli Town, Rudong County, Jiangsu Province, China
Shanghai Mintchem Development ., Ltd

Contact:0086 21 5190 8570

Address:R602,4#,89Nong, Mudan Road Pudong Shanghai China
Penglai Qianwei Chemical Co., Ltd.

Contact:86-535-3357802

Address:Shahelu (north), Penglai, Shandong, China
Hangzhou Dingyan Chem Co., Ltd

website:http://www.dingyanchem.com

Contact:86-571-87157530

Address:RM.1118,NO.1 Building, Baiyun Tower,Jianggan Area, Hangzhou city, China,310004

Relevant to this article

Enantioselective synthesis of (+)-petromyroxol, enabled by rhodium-catalyzed denitrogenation and rearrangement of a 1-sulfonyl-1,2,3-triazole

Doi:10.1021/acs.joc.5b00399
(2015)
High-performance organic semiconductors for thin-film transistors based on 2,7-divinyl[1]benzothieno[3,2-b]benzothiophene

Doi:10.1039/b808438f
(2008)
Nucleophilic substitution at the 4′-position of nucleosides: New access to a promising anti-HIV agent 2′,3′-didehydro-3′-deoxy- 4′-ethynylthymidine

Doi:10.1021/jo060194m
(2006)
Doi:10.1021/ja01559a046
(1957)
Thianthrenation-enabled α-arylation of carbonyl compounds with arenes

Doi:10.1021/acs.orglett.0c02913
(2020)
Doi:10.1021/jo01101a025
(1958)

Article Doi