Preparation of (2R,3S)-1,2-Epoxypent-4-en-3-ol, a New Chiral Building Block for the Synthesis of (+)-endo- and (-)-exo-Brevicomin

DOI: 10.1039/c39850001759

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Journal of the Chemical Society. Chemical communications p. 1759 - 1761 (1985)

Update date:2022-07-30

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Authors:

Hatakeyama, Susumi

Sakurai, Kuniya

Takano, Seiichi

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Article abstract of DOI:10.1039/c39850001759

Asymmetric epoxidation of the divinylcarbinol (7) using L-(+)-diethyl tartrate gave (2r,3S)-1,2-epoxypent-4-en-3-ol (8), which was utilized as a chiral building block in the synthesis of (+)-endo- and (-)-exo-brevicomin.

Full text of DOI:10.1039/c39850001759

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