Stereoselective synthesis of β-hydroxy-α-methylketones via z- and e-vinyloxyboranes generated directly from cyclohexyl ethyl ketone

DOI: 10.1016/S0040-4039(01)93683-4

Source and publish data:

Tetrahedron Letters p. 2229 - 2232 (1979)

Update date:2022-07-30

Topics:

Authors:

Van Horn, David E.

Masamune, Satoru

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Article abstract of DOI:10.1016/S0040-4039(01)93683-4

E- and Z-dialkylvinyloxyboranes, prepared directly from cyclohexyl ethyl ketone, undergo stereo-selective aldol condensations to provide threo- erythro-β-hydroxy-α-methylketones, respectively.

Full text of DOI:10.1016/S0040-4039(01)93683-4

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