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A Novel Route to Thiocarbonyl-Metal Complexes via Electron Transfer to (η2-CS2R)-Metal Cations

DOI: 10.1039/c39860000037

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 37 - 38 (1986)

Update date:2022-07-29

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Authors:

Touchard, Daniel

Lelay, Chantal

Fillaut, Jean-Luc

Dixneuf, Pierre H.

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Article abstract of DOI:10.1039/c39860000037

The reduction with sodium-amalgam of the cations 2-CS2Me)(CO)2L2>PF6 (1), containing basic phosphines L (PMe3, PMe2Ph, PBuⁿ3), gives rise to low-valent thiocarbonyl-iron complexes Fe(CS)(CO)2L2 (3).

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Full text of DOI:10.1039/c39860000037

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Product name:Fe(CS)(CO)2((C₆H₅)2PCH₂CH₂P(C₆H₅)2)

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