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(Phenyl)iodonium Triflate. A New and Efficient Precursor of Benzyne

DOI: 10.1039/c39950000983

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 983 - 984 (1995)

Update date:2022-07-31

Topics:

Authors:

Kitamura, TsugioKitamura, Tsugio

Yamane, MasakatsuYamane, Masakatsu

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Article abstract of DOI:10.1039/c39950000983

(Phenyl)iodonium triflate readily prepared from o-bis(trimethylsilyl)benzene and the hypervalent iodine(III) reagent shows excellent formation of benzyne under mild and neutral conditions and efficiently provides adducts with typical trapping agents, e. g. furan, anthracene, diphenylisobenzofuran and tetraphenylcyclopentadienone.

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