Synthesis and reactions of dihydrido(triethylsilyl)(1,5-cyclooctadiene)-iridium(III) complexes: Catalysts for dehydrogenative silylation of alkenes

DOI: 10.1021/om00138a046

Source and publish data:

Organometallics p. 1519 - 1520 (1986)

Update date:2022-09-26

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Authors:

Fernández, Maria J.

Esteruelas, Miguel A.

Jiménez, Maria S.

Oro, Luis A.

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Article abstract of DOI:10.1021/om00138a046

IrH₂(SiEt₃)(cod)L (L = PPh₃ or AsPh₃, cod = 1,5-cyclooctadiene) complexes have been obtained by reaction of [Ir(OMe)(cod)]₂ with L and HSiEt₃. These complexes react with PPh₃ to

Full text of DOI:10.1021/om00138a046

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