Synthesis and characterization of new rhodium and iridium complexes with trianisylphosphine, PAn3, and evaluation of their catalytic behavior in the homogeneous hydrogenation of cinnamaldehyde

DOI: 10.1016/j.molcata.2008.11.013

Source and publish data:

Journal of Molecular Catalysis A: Chemical p. 1 - 10 (2009)

Update date:2022-07-30

Topics:

Authors:

Landaeta, Vanessa R.

López-Linares, Francisco

Sánchez-Delgado, Roberto

Bianchini, Claudio

Zanobini, Fabrizio

Peruzzini, Maurizio

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Article abstract of DOI:10.1016/j.molcata.2008.11.013

A new family of rhodium and iridium compounds with the bulky tris(ortho-methoxyphenyl) phosphine (PAn₃) was synthesized and characterized by NMR methods. The X-ray crystal structures of RhCl(PAn₃)(COD) (1) and Ir[(PBz₃)(PA

Full text of DOI:10.1016/j.molcata.2008.11.013

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Product name:IrCl(tris(ortho-anisyl)phospine)(1,5-cyclo-octadiene)

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