A CHIRAL NITRONATE DIANION FROM D-GLYCERALDEHYDE. ENANTIOSPECIFIC SYNTHESIS OF 2,3-DIDEOXY-3-NITRO FURANOSIDES AND PYRANOSIDES

DOI: 10.1016/S0040-4039(01)84574-3

Source and publish data:

Tetrahedron Letters p. 6269 - 6272 (1985)

Update date:2022-07-30

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Authors:

Williams, Theresa M.

Mosher, Harry S.

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Article abstract of DOI:10.1016/S0040-4039(01)84574-3

A new enantiospecific protocol for the synthesis of 2,3-dideoxy-3-nitro and 3-amino sugars is reported.Chiral nitronate dianione 3, derived from (+)-D-glyceraldehyde, is allylated and the resulting adduct 7 is transformed to either the methyl furanoside 9

Full text of DOI:10.1016/S0040-4039(01)84574-3

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