ALDEHYDE-SELECTIVE ADDITION OF ALKYNYLCHROMIUM COMPOUNDS PREPARED BY REDUCTION OF ALKYNYL HALIDES WITH CHROMIUM(II) REAGENT

DOI: 10.1016/S0040-4039(01)80894-7

Source and publish data:

Tetrahedron Letters p. 5585 - 5588 (1985)

Update date:2022-08-04

Topics:

Authors:

Takai, Kazuhiko

Kuroda, Tooru

Nakatsukasa, Shigeki

Oshima, Koichiro

Nozaki, Hitosi

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Article abstract of DOI:10.1016/S0040-4039(01)80894-7

Alkynyl halides are reduced by chromium(II) chloride in DMF to give unisolable alkynylchromium compounds which add selectivity to an aldehyde moiety without affecting the coexisting ketone group of the substrate.

Full text of DOI:10.1016/S0040-4039(01)80894-7

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