Russian Chemical Bulletin p. 1011 - 1013 (1995)
Update date:2022-08-04
Topics:
Zaripov, R. N.
Safiullin, R. L.
Yaubasarova, E. I.
Muslukhov, R. R.
Komissarov, V. D.
The kinetics of thermal decomposition of acetylcyclohexylsulfonyl peroxide is studied in a n-decane solution in an oxygen atmosphere (303-333 K) and under anaerobic conditions (313-333 K); the reaction products are also studied in a cyclohexane solution under oxygen-free conditions (323 K).In the absence of oxygen, the reaction is found to proceed via a chain-radical mechanism.Some kinetic parameters of the process are determined. - Key words: acetylcyclohexylsulfonyl peroxide, induced decomposition.
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