HYDROXYL-DIRECTED HYDROGENATION OF HOMOALLYLIC ALCOHOLS. EFFECTS OF ACHIRAL AND CHIRAL RHODIUM CATALYSTS ON 1,3 STEREOCONTROL.

DOI: 10.1016/S0040-4039(00)95110-4

Source and publish data:

Tetrahedron Letters p. 6005 - 6008 (1985)

Update date:2022-08-04

Topics:

Authors:

Evans, D. A.

Morrissey, M. M.

Dow, R. L.

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Article abstract of DOI:10.1016/S0040-4039(00)95110-4

The hydroxyl-directed hydrogenation of homoallylic alcohols is examined with cationic rhodium-(I) and iridium-(I) catalysts.These reactions proceed with high levels of diastereoselection when either Rh(Diphos)⁺ or Ir(pry)Pcy₃^{+
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Full text of DOI:10.1016/S0040-4039(00)95110-4

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