Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 981 - 987 (1991)
Update date:2022-07-29
Topics:
Smolyakova, I. P.
Smit, V. A.
Bubnov, Yu. N.
Shashkov, A. S.
A new method is proposed for the controlled synthesis of polyfunctional compouds with formation of two new carbon-carbon bonds; the method is based on the following reaction sequence, which can be carried out in a single flask: addition of ArSCl to vinyl ether I, reaction of the resultant adduct with vinyl ether II in the presence of Lewis acid to form a cationic complex, and treatment of the latter with allyl derivatives of boron or magnesium.
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