Tetrahedron Letters p. 4071 - 4074 (1985)
Update date:2022-09-26
Topics:
Kauffmann, Thomas
Gaydoul, Klaus-Ruediger
The pentadienyllithium compounds 3, 5, 9, 12, and 15 react with ketones exclusively in α-position of the organoelement group to give the alcohols 4, 6, and 10 or the triene 13 (R = Ph), respectively.By reaction of organoelement substituted pentadienes with Na2PdCl4, Fe2(CO)9, Fe3(CO)12, and NiCl2 five well defined transition metal complexes (16-20) and three palladium clusters of unexplored structure have been obtained.From 1-(phenylthio)-2,4-pentadiene 2-(methoxy)-1-(thiophenyl)-4-pentene (23) was synthesized via palladium complex 22.
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