1,3-Dipolar Cycloaddition Reactions of Transition-Metal Carbene Complexes and the Formal Pyridinannulation of the Cycloadducts

DOI: 10.1021/ja00277a029

Source and publish data:

Journal of the American Chemical Society p. 5229 - 5236 (1986)

Update date:2022-08-04

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Authors:

Chan, Kin Shing

Wulff, William D.

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Article abstract of DOI:10.1021/ja00277a029

The first examples of 1,3-dipolar cycloadditions of α,β-unsaturated carbene complexes are described.The reaction of alkynylcarbene complexes with diazomethane gives a mixture of two products.The first arises from a <3+2> cycloaddition on the carbon-carbon

Full text of DOI:10.1021/ja00277a029

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