N-Ethyl-5-phenylisoxazolium-3'-sulfonate (Woodward's Reagent K) as a Reagent for Nucleophilic Side Chains of Proteins

DOI: 10.1021/ja00278a030

Source and publish data:

Journal of the American Chemical Society p. 5543 - 5548 (1986)

Update date:2022-08-04

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Authors:

Llamas, Kathryn

Owens, Mark

Blakeley, Robert L.

Zerner, Burt

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Article abstract of DOI:10.1021/ja00278a030

N-Ethyl-5-phenylisoxazolium-3'-sulfonate (1) is converted to the corresponding keto ketenimine in a hydroxide-promoted reaction with k_-OH=6.64E5 M^-1s^-1 at 25 deg C.The rate law for spontaneous hydration

Full text of DOI:10.1021/ja00278a030

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