
Tetrahedron Letters p. 5313 - 5316 (1985)
Update date:2022-08-03
Topics:
Takeda, Takeshi
Tsuchida, Toshio
Nakagawa, Ichiro
Ogawa, Shinji
Fujiwara, Tooru
β-Phenylthioalkyltitanium reagent prepared by the hydrotitanation of alkenyl sulfide using triethylsilane and titanium tetrachloride is found to react with aromatic aldehyde or α,β-unsaturated ketone to give the corresponding γ-hydroxyalkyl sulfide or δ-phenylthio ketone, respectively.
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