Tetrahedron Letters p. 6059 - 6062 (1985)
Update date:2022-08-04
Topics:
Weiser, Juergen
Staab, Heinz A.
The bridged porphyrin 6 was prepared via the bis(dipyrrylmethane) compounds 3, 4 and 5; by demethylation of 6 and oxidation the benzoquinone/porphyrin system 2 was obtained.The strong fluorescence quenching of 2, as compared to 6, is explained on the basis of an electron-transfer from porphyrin to quinone in S1 state.
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