Tetrahedron Letters p. 3711 - 3714 (1985)
Update date:2022-08-04
Topics:
Suzuki, Keisuke
Tomooka, Katsuhiko
Matsumoto, Takashi
Katayama, Eiji
Tsuchihashi, Gen-ichi
Two chiral intermediates, C(1)-C(9) and C(11)-C(17) portions of protomycinolide IV, were synthesized both from (S)-ethyl lactate via asymmetric pinacol-type rearrangement followed by diastereoselective reactions on α-methyl-β,γ-unsaturated carbonyl compounds.
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