Journal of Organometallic Chemistry p. 103 - 114 (1985)
Update date:2022-08-03
Topics:
Abdulla, Khalid
Booth, Brian L.
Stacey, Catherine
The comparative rates of cyclotrimerization of dimethylacetylenedicarboxylate (DMAD) and hex-3-yne have been studied with the catalysts <(η5-C5R5)Rh(COD)> (R=H, Me, Cl; COD=cycloocta-1,5-diene), <(η5-C5R5)Rh(CO)2> (R=H, Me), <(η5-C5Me5)RhL2> (L=C2H4, PF3) and <(η5-C5H4PPh3)Rh(CO)2>+ PF6- under pseudo-first-order conditions.In these reactions, which all obey the rate law, rate=kobs
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Doi:10.1246/cl.1985.1699
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