A C6,C7 Oxygen Functionalised Intermediate for the Synthesis of Forskolin: Stereochemical Control in an Intramolecular Diels Alder Reaction

DOI: 10.1016/S0040-4039(00)98284-4

Source and publish data:

Tetrahedron Letters p. 3307 - 3310 (1985)

Update date:2022-08-02

Topics:

Authors:

Ziegler, Frederick E.

Jaynes, Burton H.

Saindane, Manohar T.

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Article abstract of DOI:10.1016/S0040-4039(00)98284-4

Stereospecific intramolecular Diels-Alder reactions of aldehydes 3a and 3b afford lactones 4 and 5, respectively.The mechanism of the reactions is considered.Lactone 4 is elaborated further to provide acetonide 14b, an important intermediate in an approac

Full text of DOI:10.1016/S0040-4039(00)98284-4

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