NOVEL CYCLIC "YLIDE-CARBENE" COMPLEXES I. SYNTHESIS OF 3-(DIMETHYLPHENYLPHOSPHORANE)INDOLIDIN-2-YLIDENE COMPLEXES OF PLATINUM(II) DERIVED FROM METAL-COORDINATED PHOSPHONIUM-SUBSTITUTED ISOCYANIDE LIGANDS

DOI: 10.1016/0022-328X(85)87478-7

Source and publish data:

Journal of Organometallic Chemistry p. C21 - C25 (1985)

Update date:2022-08-02

Topics:

Authors:

Facchin, Giacomo

Campostrini, Renzo

Michelin, Rino A.

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Article abstract of DOI:10.1016/0022-328X(85)87478-7

Nucleophilic attack of NEt3 on the activated methylene group of the -CH2P⁺R3 moiety of the platinum(II)-coordinated phosphonium-substituted isocyanides o-(X^-⁺PR3CH2)C6H4NC (X=Cl, BF4; PR3=PMe2Ph) produces the highly reacti

Full text of DOI:10.1016/0022-328X(85)87478-7

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Product name:Cr(CO)5NCC₆H₄CH₂P(CH₃)2C₆H₅⁽¹⁺⁾*Cl^(1-)=[Cr(CO)5NCC₆H₄CH₂P(CH₃)2C₆H₅]Cl

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