Journal of Organic Chemistry p. 5083 - 5092 (1986)
Update date:2022-08-04
Topics:
Maruyama, Kazuhiro
Nagai, Naoshi
Naruta, Yoshinori
Rearrangement of aryl pentadienyl ethers in the presence of BF3*OEt2 affords pentadienyl phenols in good yields without formation of the corresponding <3,3> rearranged products.The mechanism of this rearrangement was studied by deuterium labeling and cross-coupling reactions.The scope and limitations of the rearrangement are discussed.
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