SYNTHESIS OF THE β-LACTAM ANTIBIOTIC (+)-THIENAMYCIN VIA AN INTERMEDIATE ?-ALLYLTRICARBONYLIRON LACTONE COMPLEXES

DOI: 10.1016/S0040-4020(01)91426-7

Source and publish data:

Tetrahedron p. 5871 - 5878 (1985)

Update date:2022-07-30

Topics:

Authors:

Hodgson, Simon T.

Hollinshead, David M.

Ley, Steven V.

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Article abstract of DOI:10.1016/S0040-4020(01)91426-7

The ?-allyltricarbonyliron lactone complex (7), formed by reaction of E-1,2-epoxy-2-methyl-6,6-dimethoxyhex-3-ene (5) with co-ordinatively unsaturated iron carbonyl species, was reacted with benzylamine to give a lactam complex (8) by an SN'-like mechanis

Full text of DOI:10.1016/S0040-4020(01)91426-7

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